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Biosorption of Cu(Ⅱ) and Pb(Ⅱ) by Auricularia polytricha
作者姓名:ZHANG  Dan  GAO  Jianwei  GAO  Tingyan  YING  Yigao  CHEN  Hong
作者单位:[1]Institute of Mountain Hazards and Environment, Chinese Academy of Sciences, Chengdu 610041,Sichuan, China [2]Institute of Geographical Sciences and Natural Resources Research, Chinese Academy of Sciences, Beijing 100101, China [3]Graduate University of Chinese Academy of Sciences, Beijing 100049, China
基金项目:Supported by the Research Foundation of Sichuan Department of Science and Technology(04SG023-006-05) and Post Doctorial Program of Institute of Mountain Hazards and Environment, CAS
摘    要:For searching biological material for heavy metal removal of waste-water, using macrofungus Auricularia polytricha as biosorbent for Cu^2+ and Pb^2+ removal was investigated. After shaking and biosorbing Cu^2+ and Pb^2+ in solution by biosorbents, the filtrates were tested by AAS and the adsorbed quantity of Cu^2+ and Pb^2+ was calculated. The biosorbents were effective in removal of Cu^2+ and Pb^2+ on the biosorbents that showed a high- est value around pH 5-6. The biosorption rate of Cu^2+ and Pb^2+ on A. polytricha biomass decreased with increasing the initial concentration of Cu^2+ and Pb^2+ in the medium. The biosorption of Cu^2+ and Pb^2+ on the biomasses follows pseudo-second order kinetics. The determined maximum biosorption capacities presented by the fungus biomass were 3.34 and 13.03 mg·g^-1 dry weight for Cu^2+ and Pb^2+, respectively by the biosorption equilibrium with Langmuir adsorption isotherm. According to the whole data analysis in each experiment of studying Cu^2+ and Pb^2+ biosorption including condition factors and adsorption isotherm, the adsorbed capacity of Pb^2+ by A. polytricha biomass was bigger than Cu^2+. The biosorption by A. polytricha was most effective when pH 5-6. The biosorbents are suitable for low Cu^2+ and Pb^2+ concentration waste-water, especially for Pb^2+ removal.

关 键 词:生物吸附作用      动力学模型  废水处理  生物材料
文章编号:1007-1202(2007)04-0755-07
收稿时间:22 November 2006
修稿时间:2006-11-22

Biosorption of Cu(II) and Pb(II) by <Emphasis Type="Italic">Auricularia polytricha</Emphasis>
ZHANG Dan GAO Jianwei GAO Tingyan YING Yigao CHEN Hong.Biosorption of Cu(II) and Pb(II) by Auricularia polytricha[J].Wuhan University Journal of Natural Sciences,2007,12(4):755-761.
Authors:Zhang Dan  Gao Jianwei  Gao Tingyan  Ying Yigao  Chen Hong
Affiliation:(1) Institute of Mountain Hazards and Environment, Chinese Academy of Sciences, Chengdu, 610041, Sichuan, China;(2) Institute of Geographical Sciences and Natural Resources Research, Chinese Academy of Sciences, Beijing, 100101, China;(3) Graduate University of Chinese Academy of Sciences, Beijing, 100049, China
Abstract:For searching biological material for heavy metal removal of waste-water, using macrofungus Auricularia polytricha as biosorbent for Cu2+ and Pb2+ removal was investigated. After shaking and biosorbing Cu2+ and Pb2+ in solution by biosorbents, the filtrates were tested by AAS and the adsorbed quantity of Cu2+ and Pb2+ was calculated. The biosorbents were effective in removal of Cu2+ and Pb2+ on the biosorbents that showed a highest value around pH 5–6. The biosorption rate of Cu2+ and Pb2+ on A. polytricha biomass decreased with increasing the initial concentration of Cu2+ and Pb2+ in the medium. The biosorption of Cu2+ and Pb2+ on the biomasses follows pseudo-second order kinetics. The determined maximum biosorption capacities presented by the fungus biomass were 3.34 and 13.03 mg · g−1 dry weight for Cu2+ and Pb2+, respectively by the biosorption equilibrium with Langmuir adsorption isotherm. According to the whole data analysis in each experiment of studying Cu2+ and Pb2+ biosorption including condition factors and adsorption isotherm, the adsorbed capacity of Pb2+ by A. polytricha biomass was bigger than Cu2+. The biosorption by A. polytricha was most effective when pH 5–6. The biosorbents are suitable for low Cu2+ and Pb2+ concentration waste-water, especially for Pb2+ removal. Biography: ZHANG Dan(1962–), female, Associate professor, Ph. D., research direction: environment engineering and soil ecology.
Keywords:Auricularia polytricha  biosorption  Pb2  Cu2  isotherm  kinetic model
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