| 邻氯苯基卟啉-奎宁季铵盐化合物的合成及表征 |
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| 引用本文： | 吴银素,刘彦钦,韩士田. 邻氯苯基卟啉-奎宁季铵盐化合物的合成及表征[J]. 化学试剂, 2001, 23(5): 267-268 |
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| 作者姓名： | 吴银素 刘彦钦 韩士田 |
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| 作者单位： | 河北师范大学化学系, |
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| 基金项目： | 河北省自然科学基金资助课题 (No.2 99194) |
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| 摘 要： | 为了寻找具有手性诱导、相转移和催化为一体的三功能卟啉催化剂,探讨氯取代基的空间位置对氯苯基卟啉－奎宁季铵盐催化性能、手性不对称诱导效应的影响,合成了邻氯苯基卟啉－奎宁季铵盐化合物,其结构用UV、IR、^1HNMR、MS和元素分析得到确证,并研究了其荧光光谱性质。
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| 关 键 词： | 合成 表征 邻氯苯基卟啉－奎宁季铵盐 卟啉催化剂 |
| 文章编号： | 0258-3283(2001)05-0267-02 |
The synthesis and characterization of o-chlorophenyl porphyrin-quinine quaternary ammonium salt |
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| Abstract: | o Chlorophenyl porphyrin quinine quaternary ammonium salt was synthesized.Its structure was confirmed by elemental analysis,IR,UV, 1HNMR and MS spectroscopy.Its fluorescence property was also studied.The purpose is to study the chiral induction,phase transfer, catalytical properties of the salt and to investigate the influence of the position of the chlorine on chlorophenyl porphyrin quinine quaternary ammonium salt in catalysis and asymmetric chiral induction. |
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| Keywords: | synthesis porphyrin quinine characterization |
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