| 牛血清蛋白催化Michael-Aldol串联反应的研究 |
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| 引用本文： | 王早,刘晨江,王吉德,王娜.牛血清蛋白催化Michael-Aldol串联反应的研究[J].化学研究与应用,2012,24(7):1155-1158. |
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| 作者姓名： | 王早 刘晨江 王吉德 王娜 |
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| 作者单位： | 1. 新疆大学化学化工学院石油和天然气精细化工教育部和新疆维吾尔自治区重点实验室,新疆乌鲁木齐,830046
2. 四川大学化学学院,绿色化学与技术教育部重点实验室,四川成都610064 |
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| 摘 要： | 首次报道了牛血清蛋白(BSA)催化二苯甲酰甲烷和丁烯酮的Michael-Aldol串联反应,并对1,3-二羰基化合物进行了研究,丁烯酮与α,β-不饱和酮酯化合物只生成一分子Michael及双分子Michael加成产物,该方法为合成环状化合物提供了新的途径。
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| 关 键 词： | BSA 1 3-二羰基化合物 丁烯酮 Michael加成反应 Aldol反应 |
BSA-catalyzed Michael-aldol cascade reaction |
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| WANG Zao
,
LIU Chen-jiang
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WANG Ji-de
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WANG Na.BSA-catalyzed Michael-aldol cascade reaction[J].Chemical Research and Application,2012,24(7):1155-1158. |
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| Authors: | WANG Zao LIU Chen-jiang WANG Ji-de WANG Na |
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| Affiliation: | 1.Key Laboratory of Oil and Gas Fine Chemicals,Ministry of Education and Xinjiang Uyghur Autonomous Region,College of Chemistry and Chemical Engineering,Xinjiang University,Urumqi 830046,China; 2.Key Laboratory of Green Chemistry and Technology,Ministry of Education,College of Chemistry,Chengdu 610064,China) |
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| Abstract: | Bovine serum albumin(BSA)was able to catalyse Michael-Aldol cascade reaction between MVK and dibenzoyl methane.Furthermore,we also studied other 1,3-dicarbonyl compounds,which gave one or two molecules Michael addition product.The method provided a new way to synthesize cyclic compounds |
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| Keywords: | BSA 1 3-dicarbonyl compounds MVK Michael addition reaction Aldol reaction |
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