| 不同氯代物及烷基铝对稀土体系催化丁二烯聚合的影响 |
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| 引用本文： | 赵春英,徐玲,仲崇祺,唐学明.不同氯代物及烷基铝对稀土体系催化丁二烯聚合的影响[J].青岛科技大学学报,1994(3). |
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| 作者姓名： | 赵春英 徐玲 仲崇祺 唐学明 |
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| 摘 要： | 讨论了不同氯代物及烷基铝对丁二烯聚合的影响，以及不同的Ｃｌ／Ｎｄ比与活性、顺丁胶微观结构之问的关系。发现Ｎｄ（ｎａｐｈ）３—氯代物—烷基铝体系的活性顺序为：ＡｌＥｔ２Ｃｌ，Ａｌ（ｉ—Ｂｕ）２Ｃｌ，倍半异丁基氯化铝＞氯硅烷≥烯丙基氯；Ａｌ（ｉ—Ｂｕ）３》ＡｌＥｔ３；Ｃｌ／Ｎｄ比在３．５～７范围内活性几乎不变；不同氯代物、烷基铝及Ｃｌ／Ｎｄ比对产物的微观结构无明显影响，但对特性粘度［η］（高聚物的分子量）影响较大。
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| 关 键 词： | 稀土催化剂 氯代物 烷基铝 丁二烯聚合 催化活性 |
Effects of Different Chloride and Aluminium Alkyl on Butadiene Polymerization with Rare Earth Catalyst System |
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| Zhao Chunying,Xu Ling,Zhong Chongqi,Tang Xueming.Effects of Different Chloride and Aluminium Alkyl on Butadiene Polymerization with Rare Earth Catalyst System[J].Journal of Qingdao University of Science and Technology:Natutral Science Edition,1994(3). |
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| Authors: | Zhao Chunying Xu Ling Zhong Chongqi Tang Xueming |
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| Affiliation: | Department of Polymer material Engineering |
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| Abstract: | The effects of different chloride and aluminium alkyl on butadiene polymerization and the relationship between the ratio of Cl/Nd and the activity and microstructure were studied. The order of the activity of Nd (Naph)3 -chloride-cluminium catalyst system is AlEt2Cl, Al (i- Bu)2Cl,Ala(i- Bu )3 Cl≥(CH3 )4-n SiCln(n = 1,2,3,4)>CH2= CH-CH2Cl and Al (i-Bu)3>>AlEt3.When the ratio of Cl/Nd ranged from 3. 5 to 7,the activity hardly changed,Variation of chloride, aluminum and ratio of Cl/Nd had no apparent effect on PB microstructure,but its effect on η]was noticeable. |
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| Keywords: | rare earth catalyst chloride aluminitum butadiene polymerization catalytic activity |
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