Proton Conductivity of Cs2MnH3(P2O7)2 and Rb2MnHP2O7(H2PO4)2 |
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| Authors: | N. N. Chudinova E. V. Murashova B. S. Zakharova V. A. Tarnopol'skii A. B. Yaroslavtsev |
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| Affiliation: | (1) Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia |
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| Abstract: | Cs2MnH3(P2O7)2 and Rb2MnHP2O7(H2PO4)2 are shown to have an appreciable proton conductivity: 5 × 10–8 and 2 × 10–5 S/cm in the Cs compound at 298 and 400 K, respectively, and 10–7 and 4 × 10–7 S/cm in the Rb compound. The conductivity and structural data are analyzed in relation to the mechanisms of protonic conduction in these mixed phosphates. |
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