| First Total Synthesis of (±)-Aiphanol |
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| 作者姓名： | Xiao Long WANG Jian Peng FENG Xin Gang XIE Xiao Ping CAO* Xin Fu PAN* |
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| 作者单位： | Xiao Long WANG，Jian Peng FENG，Xin Gang XIE，Xiao Ping CAO*，Xin Fu PAN* Department of Chemistry & State Key Laboratory of Applied Organic Chemistry，Lanzhou University，Lanzhou 730000 |
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| 摘 要： | Aiphanol was isolated from the seeds of Aiphanes aculeate Willd. (Arecaceae) collected in Peru and was reported to exhibit significant inhibitory activities against cyclooxyge- nases-1 and -2. The structure of aiphanol was elucidated by spectroscopic methods as an unprecedented stilbenolignan skeleton in which a stilbene moiety is linked to a phenylpropane unit through a dioxane bridge1. In our previous works the synthetic approach to 1,4-benzodioxane lignans were achieved2. Since aiphanol…
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