Pyrimidines |
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| Authors: | V V Lapachev O A Zagulyaeva V P Mamaev |
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| Affiliation: | 1. Institute of Organic Chemistry, Academy of Sciences of the USSR, Siberian Branch, Novosibirsk
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| Abstract: | The corresponding 2-pyrimidoylacetate esters (I, II) and 2-pyrimidoyl-acetonitrile (V) were obtained by condensation of pyrimidine-2-carboxylic acid esters with methyl acetate or acetonitrile. The structures of the tautomeric forms were determined by IR and PMR spectroscopy. The effect of a solvent and protonation of the pyrimidine ring on the ketone-enol equilibrium was examined. |
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