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从单条草中分得一个新的三萜皂苷
引用本文:张晓瑢,彭树林,王明奎,丁立生.从单条草中分得一个新的三萜皂苷[J].中草药,2002,33(6):481-483.
作者姓名:张晓瑢  彭树林  王明奎  丁立生
作者单位:中国科学院成都生物研究所,四川,成都,610041
摘    要:目的:对报春花科珍珠菜属药用植物单条草Lysimachia candida的化学成分进行研究。方法:采用硅胶柱层析进行分离和纯化,通过波谱和化学方法进行结构鉴定。结果:从正丁醇萃取部分分离出1个三萜皂苷类化合物,结构鉴定为:3β,16α-羟基齐墩果-12-烯-28-醛-3-O-β-D-吡喃葡萄糖基-23-O-α-D-呋喃核糖苷,命名为单条草苷甲(1),结论:单条草苷甲是新结构的三萜皂苷。

关 键 词:单条草  三萜皂苷  单条草苷甲  板春花科  珍珠菜属  化学成分
收稿时间:2000/10/12 0:00:00

A new triterpenoid saponin from Lysimachia candida
ZHANG Xiaorong,PENG Shulin,WANG Mingkui and Ding Lisheng.A new triterpenoid saponin from Lysimachia candida[J].Chinese Traditional and Herbal Drugs,2002,33(6):481-483.
Authors:ZHANG Xiaorong  PENG Shulin  WANG Mingkui and Ding Lisheng
Affiliation:Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu Sichuan 610041, China;Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu Sichuan 610041, China;Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu Sichuan 610041, China;Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu Sichuan 610041, China
Abstract:Object To investigate the chemical constituents from the whole plant of Lysimachia candida Ldl.. Methods The constituents were isolated and purified on silica gel column chromatography.Their structures were elucidated by chemical and spectroscopic evidence. Results A triterpenoid saponin,named candidoside A ( Ⅰ ), was isolated from the extract of n-BuOH. Its structure was shown to be 3β,16α-dihydroxy-olean-12-en-28-al-3-O-β-D-glucopyranosyl-23-O-α-D-ribofuranoside. Conclusion Candidoside A was a new triterpenoid saponin.
Keywords:Lysimachia candida Ldl    triterpenoid saponin  candidoside A
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