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Modification of surface functionality of multi-walled carbon nanotubes on fracture toughness of basalt fiber-reinforced composites
Affiliation:1. Department of Chemistry, Inha University, 100 Inharo, Incheon, Republic of Korea;2. Department of Chemistry, Chungbuk National University, Cheongju, 360-764, Republic of Korea;3. Department of Mechanical Engineering, Kyung Hee University, Yongin, 446-701, Republic of Korea;1. Fibrous Ceramics and Aerospace Materials Center, Korea Institute of Ceramic Engineering and Technology, 101 Soho-ro, Jinju-si 52851, South Korea;2. Department of Polymer Science and Engineering, Chonnam National University, 77 Buk-gu, Gwangju-si 68861, South Korea;1. Department of Chemical Engineering Materials Environment, Sapienza-Università di Roma, Via Eudossiana 18, 00184 Rome, Italy;2. Institut PPRIME, CNRS-ENSMA, Université de Poitiers, Département Physique et Mécanique des Matériaux, ENSMA, 1, Av. Clément Ader, B.P. 40109, 86961 Futuroscope Cedex, France;3. Institute of Materials Chemistry, Faculty of Chemistry, Brno University of Technology, Purkynova 118, CZ-612 00 Brno, Czech Republic;1. Department of Engineering for Innovation, University of Salento, Via per Monteroni, 73100 Lecce, Italy;2. ENEA – Italian National Agency for New Technologies, Energy and Sustainable Economic Development, Technical Unit for Materials Technologies, Brindisi Research Centre, S.S. 7, Km. 706, 72100 Brindisi, Italy
Abstract:In this work, we studied the influence of surface functionality of multi-walled carbon nanotubes (MWCNTs) on the mechanical properties of basalt fiber-reinforced composites. Acid and base values of the MWCNTs were determined by Boehm's titration technique. The surface properties of the MWCNTs were determined FT-IR, and XPS. The mechanical properties of the composites were assessed by measuring the interlaminar shear stress, fracture toughness, fracture energy, and impact strength. The chemical treatments led to a change of the surface characteristics of the MWCNTs and of the mechanical interfacial properties of MWCNTs/basalt fibers/epoxy composites. Especially the acid-treated MWCNTs/basalt fibers/epoxy composites had improved mechanical properties compared to the base-treated and non-treated MWCNTs/basalt fibers/epoxy composites. These results can probably be attributed to the improved interfacial bonding strength resulting from the improved dispersion and interfacial adhesion between the epoxy resin and the MWCNTs.
Keywords:A  Polymer-matrix composites  B  Fracture toughness  E  Surface treatments
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