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8-羟基喹哪啶螯合树脂吸附钯(Ⅱ)的性能研究
引用本文:周小华.8-羟基喹哪啶螯合树脂吸附钯(Ⅱ)的性能研究[J].贵金属,2019,40(1):25-29.
作者姓名:周小华
作者单位:昆明学院昆明滇池(湖泊)污染防治合作研究中心,昆明,650214
基金项目:昆明学院引进人才科技项目(YJL18009)、昆明滇池国家旅游度假区环保局项目(HX190001)。
摘    要:用静态法研究了8-羟基喹哪啶螯合树脂在酸性溶液中吸附和解吸Pd(II)的性能,分析了吸附等温线和吸附动力学过程。结果表明,在0.6 mol/L HCl的介质中,树脂对Pd(II)的饱和吸附量为99.46 mg/g,吸附率为94.7%,解吸率达到95.6%;吸附过程符合Langmuir和Freundlich等温吸附模型,准二级动力学Lagergren方程更适合描述此吸附过程。

关 键 词:湿法冶金  螯合树脂  吸附  Pd(Ⅱ)  动力学  模型
收稿时间:2018/11/9 0:00:00

Study on 8-Hydroxyquinoline Chelate Resin's Adsorption Property for Pd(II)
ZHOU Xiaohua.Study on 8-Hydroxyquinoline Chelate Resin's Adsorption Property for Pd(II)[J].Precious Metals,2019,40(1):25-29.
Authors:ZHOU Xiaohua
Affiliation:Kunming Cooperative Research Center for Pollution Prevention of Dianchi Lake, Kunming University, Kunming 650214, China
Abstract:The property of 8-hydroxyquinoline chelate resin (PS-HQD) for adsorption and desorption Pd(II) from solution were studied with static adsorption, andthe adsorption isotherm and kinetics were analyzed. The results showed that saturated adsorption capacity was 99.46 mg/g, adsorption and desorbtion rate of PS-HQD could reach 94.7% and 95.6% in 0.6 mol/L HCl solution, respectively. The equilibrium adsorption followed to both Langmuir and Freundlich isotherms models, and the Lgergren pseudo-second order kinetic model was more suitable for describing the adsorption process.
Keywords:hydrometallurgy  chelate resin  adsorption  kinetics  Pd(II)  model
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