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Synthesis and properties of Au-Fe3O4 and Ag-Fe3O4 heterodimeric nanoparticles
作者姓名:丁皓  申承民  惠超  徐梽川  李晨  田园  时雪钊  高鸿钧
作者单位:Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
基金项目:Project supported by the National Natural Science Foundation of China (Grant Nos.~60571045 and 50872147) and the National High-Tech. Research and Development Program of China (Grant No.~2007AA03Z035).
摘    要:Monodisperse Au-Fe 3 O 4 heterodimeric nanoparticles (NPs) were prepared by injecting precursors into a hot reaction solution.The size of Au and Fe 3 O 4 particles can be controlled by changing the injection temperature.UV-Vis spectra show that the surface plasma resonance band of Au-Fe 3 O 4 heterodimeric NPs was evidently red-shifted compared with the resonance band of Au NPs of similar size.The as-prepared heterodimeric Au-Fe 3 O 4 NPs exhibited superparamagnetic properties at room temperature.The Ag-Fe 3 O 4 heterodimeric NPs were also prepared by this synthetic method simply using AgNO 3 as precursor instead of HAuCl 4.It is indicated that the reported method can be readily extended to the synthesis of other noble metal conjugated heterodimeric NPs.

关 键 词:heterodimeric  structure  monodisperse  Au-Fe  3  O  4  nanoparticles
收稿时间:2009-09-10

Synthesis and properties of Au-Fe3O4 and Ag-Fe3O4 heterodimeric nanoparticles
Ding Hao,Shen Cheng-Min,Hui Chao,Xu Zhi-Chuan,Li Chen,Tian Yuan,Shi Xue-Zhao and Gao Hong-Jun.Synthesis and properties of Au-Fe3O4 and Ag-Fe3O4 heterodimeric nanoparticles[J].Chinese Physics B,2010,19(6):66102-066102.
Authors:Ding Hao  Shen Cheng-Min  Hui Chao  Xu Zhi-Chuan  Li Chen  Tian Yuan  Shi Xue-Zhao and Gao Hong-Jun
Affiliation:Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
Abstract:Monodisperse Au--Fe$3O4 heterodimeric nanoparticles (NPs) were prepared by injecting precursors into a hot reaction solution. The size of Au and Fe$3O4 particles can be controlled by changing the injection temperature. UV--Vis spectra show that the surface plasma resonance band of Au--Fe$3O4 heterodimeric NPs was evidently red-shifted compared with the resonance band of Au NPs of similar size. The as-prepared heterodimeric Au--Fe$3O4 NPs exhibited superparamagnetic properties at room temperature. The Ag--Fe$3O4 heterodimeric NPs were also prepared by this synthetic method simply using AgNO$3 as precursor instead of HAuCl4. It is indicated that the reported method can be readily extended to the synthesis of other noble metal conjugated heterodimeric NPs.
Keywords:heterodimeric structure  monodisperse  Au--Fe$3O4 nanoparticles
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