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| Pd(OAc)_2/P(t-Bu)_3催化合成空穴传输材料APB的研究 | |
| 引用本文： | 韩巧玲,张玉祥,李祥国. Pd(OAc)_2/P(t-Bu)_3催化合成空穴传输材料APB的研究[J]. 应用化工, 2007, 36(1): 35-37 |
| 作者姓名： | 韩巧玲 张玉祥 李祥国 |
| 作者单位： | 1. 西安建筑科技大学,理学院,陕西,西安,710055 2. 西安建筑科技大学,理学院,陕西,西安,710055;西安瑞联近代电子材料有限责任公司,陕西,西安,710065 3. 西安正源新燃料发展有限公司,陕西,西安,710015 |
| 摘 要： | 以二苯基联苯二胺(DPB)和9-溴蒽为原料,在叔丁醇钠强碱环境下,以Pd(OAc)2/P(t-Bu)3为催化剂合成了新型空穴传输材料N,N’-二苯基-N,N’-二蒽基-1,1’-联苯-4,4’-二胺(APB)。得到优化的催化反应条件为:以二甲苯为溶剂在130~138℃回流反应3 h,Pd(OAc)2∶P(t-Bu)3=1∶1.2(摩尔比),P(t-Bu)3/9-溴蒽=0.24%;经元素分析、GC-MS、1H NMR等表征了结构;差示扫描量热仪(DSC)分析结果显示其熔点为324℃,具有良好的热稳定性。 |
| 关 键 词： | 空穴传输材料 Pd(OAc)2/P(t-Bu)3催化 热稳定性 |
| 文章编号： | 1671-3206（2007）01-0035-03 |
| 修稿时间： | 2006-11-06 |
Study on synthesis of novel hole transporting materials APB by the catalyst of Pd(OAc )2/P(t-Bu )3 |
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| HAN Qiao-ling,ZHANG Yu-xiang,LI Xiang-guo. Study on synthesis of novel hole transporting materials APB by the catalyst of Pd(OAc )2/P(t-Bu )3[J]. Applied chemical industry, 2007, 36(1): 35-37 | |
| Authors: | HAN Qiao-ling ZHANG Yu-xiang LI Xiang-guo |
| Abstract: | Novel hole transporting material APB were synthesized with 9-bromoanthracene and arkylamine DPB as raw materials in the mixture catalyst of sodium tert-butoxide,Pd(OAc)_2/P(t-Bu) system.The best reaction conditions have been confirmed:using dimethyl benzene as solvent,refluxed for 3 h at 130～138 ℃,n[Pd(OAc)_2]∶ n[P(t-Bu)_3] is 1∶1.2,(n[P(t-Bu)_3])/n(9-dibromoanthracene) is(0.24%.)Structures were characterized by elemental analysis,GC-MS,~1H NMR,etc.The melting point were measured by DSC is 324 ℃,it has good thermal stability. |
| Keywords: | hole transport material Pd(OAc)_2/P(t-Bu)_3 catalysis thermal stability |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |
