| 几种新型卟啉的合成及其光敏性质 |
| |
| 引用本文： | 刘玉文,王永强.几种新型卟啉的合成及其光敏性质[J].高等学校化学学报,1993,14(12):1647-1650. |
| |
| 作者姓名： | 刘玉文 王永强 |
| |
| 作者单位： | 吉林大学化学系，吉林大学化学系，吉林大学化学系，吉林大学化学系，吉林大学化学系，吉林大学化学系 长春 130023，长春 130023，长春 130023，长春 130023，长春 130023，长春 130023 |
| |
| 摘 要： | 合成了４种新的卟啉配体及其锌的配合物，并用红外光谱、紫外可见光谱、元素分析等手段对它们进行了表征。初步实验表明所合成的卟啉配体和金属卟啉均具有光敏性。
|
| 关 键 词： | 卟啉 光敏剂 |
The Synthesis of Some New Type Porphyrins and Their Photosensitivities |
| |
| LIU Yu-Wen,WANG Yong-Qiang,WANG Xing-Qiao,WANG Li-BoYU Lian-Xiang,CAO Xi-Zhang.The Synthesis of Some New Type Porphyrins and Their Photosensitivities[J].Chemical Research In Chinese Universities,1993,14(12):1647-1650. |
| |
| Authors: | LIU Yu-Wen WANG Yong-Qiang WANG Xing-Qiao WANG Li-BoYU Lian-Xiang CAO Xi-Zhang |
| |
| Abstract: | Four new porphyrins, TIAPP, TNAPP, TMIAPPI, IMNAPPI,and two of their zinc complexes, ZnTMIAPPI, ZnTMNAPPI, are synthesized. Four porphyrins can be dissolved in water. Their structures are characterized by IR, UV-Vis and elementary analysis.Using triethanolamine as donor, porphyrin as photosensitizer and methyl viologen(MV2+) as receptor, the photosensitizing reaction of the four kinds of water-soluable porphyrins is conducted in DMSO-H2O system. The results show that all of these new porphyrins possess photo-sensitivity. Among them, zinc porphyins are the best. They have the following order; ZnTMIAPPI> ZnTMN APPI>TMIAPPI>TMN APPI. |
| |
| Keywords: | Porphyrin Photosensitizer Complex |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
