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| 星状C60(CH3)x(PAN)x共聚物的光致发光研究 | |
| 引用本文： | 马国宏,钱士雄,陈彧,蔡瑞芳,赵太平,叶学敏.星状C60(CH3)x(PAN)x共聚物的光致发光研究[J].光谱学与光谱分析,2000,20(3):270-272. |
| 作者姓名： | 马国宏 钱士雄 陈彧 蔡瑞芳 赵太平 叶学敏 |
| 作者单位： | 1. 复旦大学物理系,200433,上海 2. 复旦大学化学系,200433,上海 3. 北京大学物理系,100871,北京 |
| 基金项目： | 国家自然科学基金，上海应用物理中心联合资助项目，69687004;29890216，97JC19018，， |
| 摘 要： | 利用物理喷束淀积（ＰＪＤ）技术制备Ｃ６０（ＣＨ３）ｘ（ＰＡＮ）ｘ共聚物的薄膜。这种共聚物中，Ｃ６０分子位于星状结构的中心，聚丙烯腈（ＰＡＮ）主链修饰在Ｃ６０分子的周围。吸收及荧光光谱表明：Ｃ６０分子与聚丙烯腈（ＰＡＮ）有明显的相互作用，而且这种相互作用与ＰＡＮ的链长有关。Ｃ６０分子与ＰＡＮ间存在一定的激发传递过程，从而导致ＰＡＮ荧光的部分猝灭。 |
| 关 键 词： | 富勒烯 共聚物 激发传递 光致发光 聚丙烯腈 |
Photoluminescence Study of Star-like C60(CH3)x(PAN)x Copolymer |
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| Guohong MA,Shixiong QIAN,Yu CHEN,Ruifang CAI,Taiping ZHAO,Xuemin YE.Photoluminescence Study of Star-like C60(CH3)x(PAN)x Copolymer[J].Spectroscopy and Spectral Analysis,2000,20(3):270-272. | |
| Authors: | Guohong MA Shixiong QIAN Yu CHEN Ruifang CAI Taiping ZHAO Xuemin YE |
| Affiliation: | Department of Physics, Fudan University, 200433 Shanghai. |
| Abstract: | Thin film of new synthesized C 60(C H 3) x (PAN) x copolymer was fabricated by physical jet deposition (PJD) technique.C 60 molecule lies in the center of the s tar-like copolymers.PAN main chain is modified around the C 60 molecule s.Absorption and photoluminescence spectra show that there are strong interactio n between C 60 molecule and PAN,which depends on the length of PAN chain .Partly excitation transfer process between C 60 molecule and PAN was obs erved,which leads to the fluorescence quenching of the PAN. |
| Keywords: | Fullerene Copolymer Excitation transfer Ph otoluminescence |
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