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硼改性酚醛树脂的合成
引用本文:霍靓靓,朱靖,尹红娜,赵献增,王冬梅.硼改性酚醛树脂的合成[J].河南科学,2007,25(2):204-207.
作者姓名:霍靓靓  朱靖  尹红娜  赵献增  王冬梅
作者单位:1. 河南工业大学,化学化工学院,郑州,450052
2. 河南省商业科学研究所,有限责任公司,郑州,450002
3. 河南省精细化工重点实验室,郑州,450002
摘    要:通过在一定条件下,先将苯酚、甲醛制成羟甲基酚,然后改变条件与硼酸共聚,制得具有合成稳定和较好耐热性的硼改性酚醛共聚树脂.探讨催化剂种类、酚醛比、硼酸加入量等对其性能的影响.用红外光谱和热分析手段对该改性树脂的结构和热性能进行了分析表征.

关 键 词:酚醛树脂  硼改性  三元共聚
文章编号:1004-3918(2007)02-0204-04
修稿时间:2006-11-20

Synthesis of Phenolic Resin Modified with Boron
HUO Liang-liang,ZHU Jing,YIN Hong-na,ZHAO Xian-zeng,WANG Dong-mei.Synthesis of Phenolic Resin Modified with Boron[J].Henan Science,2007,25(2):204-207.
Authors:HUO Liang-liang  ZHU Jing  YIN Hong-na  ZHAO Xian-zeng  WANG Dong-mei
Affiliation:1. Henan Industry University, Zhengzhou 450052, China; 2. The Commercial Scientific Research I,imit Companise of Henan Province, Zhengzhou 450002, China; 3. Henan Key Laboratory of Fine Chemicals, Zhengzhou 450002, China
Abstract:Boracic modified penolic resin with boracic acid and hydroxymethyl phenol was manufactured after hydroxymethyl phenol was created with in a special way.The influences which caused by the kinds of the catalyzer,phenol and formaldehyde proportion,boracic acid addition and etc were discussed.The structure of the resin and its thermo capability were analyzed and characterized by IR and thermoanalysis.
Keywords:penolic resin  boracic modified  ternary polymerization
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