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LiFePO4/C电池循环性能和安全性能的研究
引用本文:武雪峰,王振波. LiFePO4/C电池循环性能和安全性能的研究[J]. 电池工业, 2010, 15(3): 156-159
作者姓名:武雪峰  王振波
作者单位:哈尔滨工业大学化工学院,黑龙江,哈尔滨,150001;哈尔滨工业大学化工学院,黑龙江,哈尔滨,150001
基金项目:国家自然科学基金,教育部留学归国科研启动基金,黑龙江省留学人员科学基金 
摘    要:以磷酸铁锂(LiFePO4/C)为正极活性物质、石墨为负极物质组装成动力锂离子电池。详细研究了该电池的循环性能以及过充电对电池安全性能的影响。对电池充放电容量、循环性能和电压衰减进行测试。研究表明:LiFePO4/C电池在常温下具有较好的循环性能,但大电流放电性能欠佳;在低温状态下电池的容量和循环性能明显下降;频繁的过充电会导致LiFePO4/C电池的循环性能降低;大电流、高电压过充电对电池的性能影响最大,电池存在的安全隐患最多。以3C2 A电流过充电时对电池的影响最大;使用LiFePO4/C材料做为动力电池的正极材料时须避免过充电现象发生。

关 键 词:锂离子电池  低温性能  过充  循环性能  LiFePO4

Investigation on cyclic and safety performance of LiFePO_4/C battery
WU Xue-feng,WANG Zhen-bo. Investigation on cyclic and safety performance of LiFePO_4/C battery[J]. Chinese Battery Industry, 2010, 15(3): 156-159
Authors:WU Xue-feng  WANG Zhen-bo
Affiliation:WU Xue-feng,WANG Zhen-bo(School of Chemical Engineering , Technology,Harbin Institute of Technology,Harbin,Heilongjiang 150001,China)
Abstract:Cyclic performance and effect of overcharge on safety performance of Li-ion battery prepared with LiFePO4/C as anode material and graphite as cathode material were studied in this paper.Chargedischarge capacity,cyclic performance and voltage decay were tested.The results showed that the cyclic performance of LiFePO4/C was relatively good at room temperature.However,its high-current discharge performance was poor.Its cyclic performance evidently deteriorated at low-temperature and its capacity markedly decli...
Keywords:LiFePO4
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