| 新型芳香二胺的合成及其聚酰亚胺的应用研究 |
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| 引用本文： | 严辉,范和平. 新型芳香二胺的合成及其聚酰亚胺的应用研究[J]. 绝缘材料, 2007, 40(1): 48-50,54 |
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| 作者姓名： | 严辉 范和平 |
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| 作者单位： | 湖北省化学研究院,武汉,430074;湖北省化学研究院,武汉,430074 |
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| 摘 要： | 首先通过双酚A和碳酸钾反应得到酚钾盐,与间-二硝基苯反应合成2,2-双[4-(3-硝基苯氧基)苯基]丙烷(3-BNPP),再用水合肼还原得到新型芳香二胺单体2,2-双[4-(3-氨基苯氧基)苯基]丙烷(3-BAPP)。用3-BAPP与多种二酐合成出多种聚酰亚胺,并在二层法挠性覆铜板(2L-FCCL)的应用方面做了一些研究。研究表明其相应的2L-FCCL具有良好的耐锡焊性能和较低的吸水率。
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| 关 键 词： | 2 2-双[4-(3-氨基苯氧基)苯基]丙烷 聚酰亚胺 合成 挠性覆铜板 |
| 文章编号： | 1009-9239（2007）01-0048-04 |
| 修稿时间： | 2006-07-312006-08-28 |
Synthesis and Properties of a Novel Aromatic Diamine and its Polyimide |
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| YAN Hui,FAN He-ping. Synthesis and Properties of a Novel Aromatic Diamine and its Polyimide[J]. Insulating Materials, 2007, 40(1): 48-50,54 |
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| Authors: | YAN Hui FAN He-ping |
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| Affiliation: | Hubei Research Institute of Chemistry, Wuhan 430074, China |
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| Abstract: | After bisphenol-A reacting to potassium carbonate, 1,3-dinitrobenzene was added, and 2,2-bis[4-(3- nitrophenyloxy)phenyl] propane(3-BNPP) was synthesized. Then 3-BNPP was reduced with Hydrazine hydrate, and a novel diamine monomer 2,2-bis[4-(3-aminophenyloxy)phenyl] propane(3-BAPP) was obtained. Various polyimide was synthesized from 3-BAPP with various dianhydrides. The application of the polyimiders to two-layer flexible copper clad laminate(2L-FCCL)was researched. The results showe the 2L-FCCL have excellent solder resistance and lower water-absorption. |
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| Keywords: | 2 2-bis[4-(3-aminophenyloxy)phenyl] propane polyimide Synthesis flexible copper clad laminate |
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