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High energy-storage properties of [(Bi1/2Na1/2)0.94 Ba0.06] La(1−x) ZrxTiO3 lead-free anti-ferroelectric ceramics
Authors:Yongfeng Wang  Zhenlin Lv  Hui Xie  Jing Cao
Affiliation:1. School of Materials Science and Engineering, Xi''an University of Technology, Xi''an 710048, PR China;2. School of Mechanical Engineering, Xi''an Aeronautical University, Xi''an 710077, PR China
Abstract:Energy-storage properties of (Bi1/2Na1/2)0.94Ba0.06]La(1−x)ZrxTiO3 (BNT-BLZT, x=0, 0.02, 0.04, and 0.06) lead-free anti-ferroelectric ceramics fabricated via the conventional sintering technique were first investigated. Calculation from the X-ray diffraction results reveals that BNT-BLZT ceramic possesses a single perovskite structure phase. In addition, the P–E hysteresis loops measured at room temperature show that the BNT-BLZT (x=0.02) ceramics obtain the maximum P value of 37.5 μC/cm2 and the largest energy-storage density Wmax is 1.58 J/cm3. The temperature dependence of dielectric permittivity εr and dielectric loss tanδ illustrate that the addition of Zr can improve the piezoelectric properties of BT-BLZT ceramics. These properties indicate that BNT-BLZT ceramics might be a promising lead-free anti-ferroelectric material for energy storage application.
Keywords:A  Ceramics  C  X-ray diffraction  D  Energy storage
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