| 含吡啶酰胺基双Schiff碱的过渡金属配合物的合成 |
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| 引用本文： | 蔡丽华,黄丽芬,朱静静,封孝华. 含吡啶酰胺基双Schiff碱的过渡金属配合物的合成[J]. 精细石油化工, 2010, 27(2) |
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| 作者姓名： | 蔡丽华 黄丽芬 朱静静 封孝华 |
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| 作者单位： | 1. 中南民族大学工商学院环境生物系,湖北,武汉,430065
2. 武汉大学化学与分子科学学院,湖北,武汉,430072 |
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| 摘 要： | 实验先合成了新的多齿Schiff配体N,N′-双(2,4-二羟基苯甲醛亚胺基乙基)-2,6-吡啶二甲酰胺(IIa),再合成了6种新的过渡金属配合物,并通过元素分析、红外光谱、紫外光谱、质谱及核磁共振等测试手段对配体及配合物进行了表征,并对配合行了合理的结构推测。
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| 关 键 词： | Schiff碱 多齿配体 过渡金属 配合物 吡啶双酰胺 |
SYNTHESIS OF OPEN RING COMPLEXES FORMED IN REACTION OF TRANSITION METALS WITH SCHIFF BASE CONTAINING PYRIDINE RING AND AMIDE BRIDGE |
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| Cai Lihua,Huang Lifen,Zhu Jingjing,Feng Xiaohua. SYNTHESIS OF OPEN RING COMPLEXES FORMED IN REACTION OF TRANSITION METALS WITH SCHIFF BASE CONTAINING PYRIDINE RING AND AMIDE BRIDGE[J]. Speciality Petrochemicals, 2010, 27(2) |
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| Authors: | Cai Lihua Huang Lifen Zhu Jingjing Feng Xiaohua |
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| Affiliation: | Cai Lihua~1,Huang Lifen~1,Zhu Jingjing~1 and Feng Xiaohua~2 (1.Engineering and Commerce College of South-Central University for Nationalities,Wuhan 430073,Hubei,China,2.College of Chemistry and Molecular Sciences,Wuhan University,Wuhan 430072,China) |
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| Abstract: | Linear multidentate Schiff base ligand [N,N-bis(2 ,4-dihydroxyphenyl-iminoethyl)-2 ,6-pyridinedicarboxylic diamide (Ⅱa)] was synthesized.It was used to prepare 6 new transition metal complexes linked by this Shiff base. The ligand and complexes were characterized by elemental analysis, IR,UV-VIS,MS and ~1H NMR.The rational structures of them were predicated. |
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| Keywords: | Schiff base polydentate ligand transition metals complex pyridinedicarboxylic diamide |
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