An unexpected oxidation of unactivated methylene C-H using DIB/TBHP protocol |
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| Authors: | Zhao Yi Yim Wai-Leung Tan Chong Kiat Yeung Ying-Yeung |
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| Affiliation: | Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543. |
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| Abstract: | An in situ generated hypervalent iodine species, bis(tert-butylperoxy)iodobenzene, was used as a peroxy radical source for the oxidation of unreactive, remote, and isolated alkyl (cyclic or aliphatic) esters and amides to the corresponding keto compounds under very mild conditions. |
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