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321不锈钢在淡化海水中的耐腐蚀性能
引用本文:吴恒,王佳,李超,张波.321不锈钢在淡化海水中的耐腐蚀性能[J].腐蚀科学与防护技术,2012(3):209-212.
作者姓名:吴恒  王佳  李超  张波
作者单位:中国海洋大学化学化工学院;金属腐蚀与防护国家重点实验室;钢铁研究总院青岛海洋腐蚀研究所
摘    要:采用电化学测试和慢应变速率拉伸(SSRT)方法,结合扫描电镜(SEM)评价321不锈钢在淡化海水中的耐蚀性.循环伏安实验表明,随着温度的升高,点蚀击破电位负移,耐点蚀性能下降;321不锈钢在淡化海水中的临界点蚀温度(CPT)为30.5℃.SSRT实验结果表明,321不锈钢在淡化海水中具有一定的应力腐蚀开裂(SCC)敏感性,随着温度的升高,应力腐蚀敏感性增大.在35℃和50℃,321不锈钢在淡化海水中的断裂为韧性断裂;而在70℃,断口微观形貌呈现韧窝+少量准解理形貌,SCC敏感性增强.

关 键 词:不锈钢  淡化海水  点蚀击破电位  临界点蚀电位  慢应变速率拉伸

Corrosion Behavior of 321 Stainless Steel in Desalinated Seawater
WU Heng,WANG Jia,LI Chao,ZHANG Bo.Corrosion Behavior of 321 Stainless Steel in Desalinated Seawater[J].Corrosion Science and Protection Technology,2012(3):209-212.
Authors:WU Heng  WANG Jia  LI Chao  ZHANG Bo
Affiliation:1.College of Chemistry and Chemical Engineering,Ocean University of China,Qingdao 266100;2.State Key Laboratory for Corrosion and Protection,Shengyang 110015;3.Qingdao Research Institute for Marine Corrosion,Central Institute for Iron and Steel,Qingdao 266071
Abstract:Electrochemical measurement,slow strain rate test and SEM observation of fracture surfaces were used to study the corrosion behavior of 321 stainless steel in desalinated seawater.The result of cyclic voltammetry indicates that the pitting potential goes negative with the temperature rising,and thereby the pitting corrosion resistance decreases.Critical pitting temperature(CPT) of 321 stainless steel is 30.5 ℃ in desalinated seawater.SSRT results show that 321 stainless steel is relatively sensitive in desalinated seawater.At 35 ℃ and 50 ℃,321 stainless steel shows ductile fracture,however the fractured surfaces exhibit ductile plus quasi-cleavage fracture at 70 ℃,and the sensitivity of SCC is inceraesed.
Keywords:stainless steel  desalinated seawater  pitting potential  critical pitting temperature  slow strain rate test
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