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水热处理抗生素菌渣制备固体生物燃料
引用本文:张光义,马大朝,彭翠娜,许光文. 水热处理抗生素菌渣制备固体生物燃料[J]. 化工学报, 2013, 64(10): 3741-3749. DOI: 10.3969/j.issn.0438-1157.2013.10.035
作者姓名:张光义  马大朝  彭翠娜  许光文
作者单位:1. 中国科学院过程工程研究所多相复杂系统国家重点实验室, 北京 100190;2. 东京工业大学, 神奈川 226-8503, 日本
基金项目:国家高技术研究发展计划项目(2012AA021402);国家自然科学基金项目(21161140329)~~
摘    要:以生物超胶体形式存在的抗生素菌渣既是一种危害严重的环境污染物又是一种生物质资源,但因高含水且难以机械脱除而制约其处理和高效利用。借助水热技术,抗生素菌渣的沉淀、脱水及干燥性能得以显著改善,获得的固体生物燃料固含率和热值随水热处理温度和历时的增加而增大,但过于苛刻的水热条件易生成焦油甚至发生碳化。在优化的水热条件200℃、30~60 min下,固体生物燃料固含率52%~55%(质量分数,下同)、热值约14 MJ·kg-1,固体回收率65%~75%。通过部分转化非凯氏有机氮(NKON)为凯氏有机氮(KON)并最终主要以氨氮(NH4+-N)形式进入液相的迁移途径,菌渣中45%以上的氮在水热处理过程中被脱除。经水热无害化处理的抗生素菌渣液体产物的COD高于20×104 mg·L-1,具备良好的生物气生产潜力。水热技术被证实是针对包括抗生素菌渣在内的生物发酵制药过程残渣无害化处理和资源化利用预处理的有效技术。

关 键 词:水热处理  脱水  发酵过程残渣  抗生素菌渣  生物燃料  
收稿时间:2013-02-25
修稿时间:2013-05-06

Hydrothermal treatment of antibiotic mycelial dregs for solid bio-fuel preparation
ZHANG Guangyi;MA Dachao;PENG Cuina;XU Guangwen. Hydrothermal treatment of antibiotic mycelial dregs for solid bio-fuel preparation[J]. Journal of Chemical Industry and Engineering(China), 2013, 64(10): 3741-3749. DOI: 10.3969/j.issn.0438-1157.2013.10.035
Authors:ZHANG Guangyi  MA Dachao  PENG Cuina  XU Guangwen
Affiliation:1. State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;2. Department of Environmental Science and Technology, Tokyo Institute of Technology, Kanagawa 226-8503, Japan
Abstract:Antibiotic mycelial dregs,existing as biomass supra-colloids,are not only a kind of serious hazardous pollutants but also a kind of biomass resource.Their treatment and utilization,however,are greatly hindered because of their high water content and poor mechanical dewatering property.The results shows that hydrothermal treatment of the dregs remarkably improved their sedimentation,dewatering and drying properties.The solid content and heating value of solid bio-fuel obtained greatly increase with going up temperatures and extending hydrothermal treatment,but it was found that tar and even carbonization of the material took place at too high temperatures.The optimized conditions gained are at 200℃ for 30-60 min,and solid bio-fuels produced had solid contents of 52%-55%(mass) and heat values of about 14 MJ·kg-1.The solid recovery ratios fell in 65%-75%,and over 45% nitrogen in raw antibiotic mycelial dreg was removed via converting a part of non-Kjeldahl organic nitrogen(NKON)into Kjeldahl organic nitrogen(KON).As the form of ammonia nitrogen(NH4+-N),most of removed nitrogen was dissolved in liquid product after hydrothermal treatment.The CODs of the liquid products were above 200000 mg·L-1,which can be good feedstock for bio-gas production.These results demonstrate actually that hydrothermal treatment would be an effective way to safely dispose and pretreat process residues from bio-pharmaceuticals industries like antibiotic mycelial dregs.
Keywords:hydrothermal treatment  dewatering  fermentative process residue  antibiotic mycelial dreg  bio-fuel  
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