| 共轭二烯烃在醚化条件下的聚合 |
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| 引用本文： | 王海彦,马骏,张少华,张永兴,孙桂大,周定.共轭二烯烃在醚化条件下的聚合[J].石油化工,1999,28(7):432-434. |
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| 作者姓名： | 王海彦 马骏 张少华 张永兴 孙桂大 周定 |
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| 作者单位： | 1. 抚顺石油学院石油化工系,辽宁省抚顺,113001
2. 哈尔滨工业大学应用化学系,哈尔滨150001 |
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| 基金项目： | 中国石油化工集团公司资助 |
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| 摘 要： | 在一连续的固定床反应器中，采用强酸性阳离子交换树脂催化剂，研究了共轭二烯烃在醚化条件下的反应行为。考察了各种反应条件对共轭二烯烃聚合反应转化率的影响。结果表明，反应温度、空速和醇烯物质的量比对共轭二烯烃聚合反应有较大影响。结合试验结果对共轭二烯烃的聚合反应机理进行了探讨
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| 关 键 词： | 共轭二烯烃 聚合 醚化 阳离子交换树脂 |
| 修稿时间： | 1998－03－09 |
Polymerization of Conjugated Dienes under Etherification Conditions |
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| WANG Hai-yan,MA Jun,ZHANG Shao-hua,ZHANG Yong-xing,SUN Gui-da,ZHOU Ding.Polymerization of Conjugated Dienes under Etherification Conditions[J].Petrochemical Technology,1999,28(7):432-434. |
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| Authors: | WANG Hai-yan MA Jun ZHANG Shao-hua ZHANG Yong-xing SUN Gui-da ZHOU Ding |
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| Abstract: | The polymerization of conjugated dienes on a cationic exchange resin was investigated.Experiments were performed in a continuous fixed reactor.It is found that temperature,space velocity,and methanol/inhibiter have major influence on the polymerization of conjugated dienes.The polymerization mechanism of conjugated dienes is discussed. |
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| Keywords: | conjugated dienes polymerization etherification cationic exchange resin |
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