| 3-氨基-4-(叔丁基氧化偶氮基)呋咱的合成与表征 |
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| 引用本文： | 李祥志,王伯周,李辉,李亚南,毕福强. 3-氨基-4-(叔丁基氧化偶氮基)呋咱的合成与表征[J]. 化学试剂, 2012, 34(9): 839-841 |
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| 作者姓名： | 李祥志 王伯周 李辉 李亚南 毕福强 |
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| 作者单位： | 西安近代化学研究所,陕西西安,710065 |
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| 基金项目： | 国防科工局基础科研计划项目 |
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| 摘 要： | 以3,4-二氨基呋咱(DAF)为起始原料,苯为反应介质,经Caro’s酸氧化得到3-氨基-4-亚硝基呋咱,然后与N,N-二溴-叔丁基胺缩合得到标题化合物,总收率37.6%,并采用红外光谱、核磁共振、元素分析及质谱等进行了结构表征。优化了反应条件,确定适宜的反应条件为:氯化亚铜作为催化剂,反应时间16 h,温度15～25℃,收率73.5%。
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| 关 键 词： | 3-氨基-4-(叔丁基氧化偶氮基)呋咱 合成 表征 |
Synthesis and characterization of 3-amine-4-( tert-butyl amine ) azoxy-furazane |
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| LI Xiang-zhi , WANG Bo-zhou , LI Hui , LI Ya-nan , BI Fu-qiang. Synthesis and characterization of 3-amine-4-( tert-butyl amine ) azoxy-furazane[J]. Chemical Reagents, 2012, 34(9): 839-841 |
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| Authors: | LI Xiang-zhi WANG Bo-zhou LI Hui LI Ya-nan BI Fu-qiang |
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| Affiliation: | (Xi′an Modern Chemistry Research Institute,Xi′an 710065,China) |
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| Abstract: | The 3-amino-4-(tert-butyl amine)azoxyfurazane was synthesized using 3,4-diaminofurazan via oxidation and condensation with the total yield of 37.6%.The title compound and intermediate were characterized by 1HNMR,IR,MS and elementary analysis.The conditions of condensation were optimized such as cuprous chloride as catalyst and the reaction time of 16 h and temperature of 15~25 ℃.The yield can reach 73.5%. |
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| Keywords: | 3-amine-4-(tert-butyl amine)azoxyfurazane synthesis characterization |
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