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Al/C/Fe复合电极电絮凝法同时除氟除砷(V)
引用本文:齐学谦,李泽唐,周雅芳,张旭.Al/C/Fe复合电极电絮凝法同时除氟除砷(V)[J].环境污染治理技术与设备,2014(2):525-530.
作者姓名:齐学谦  李泽唐  周雅芳  张旭
作者单位:[1]清华大学环境学院,北京100084 [2]铁岭天信公用事业股份有限公司,铁岭112000
基金项目:国家“水体污染控制与治理”科技重大专项(2009zx07425-006);环保公益性行业科研专项(201009009-003)
摘    要:为了同时去除地下水中的氟和砷,提出了Al/C/Fe复合电极电絮凝法和Al/C—Fe/C依次除氟砷法,并进行效果对比。研究了Al/C/Fe复合电极电絮凝法的影响因素,并对复合电极电絮凝产生的絮体进行了SEM-EDX分析。结果表明,Al/C/Fe复合电极电絮凝法对氟、砷的去除速率分别是Al/C-Fe/C依次除氟砷法的1.43倍和4.73倍;初始氟/砷浓度为4.0/1.0、4.0/0和0/1.0mg/L3种条件下,通过铝极板、铁极板的电流密度均为0.10mA/cm2时,达到最好的除氟除砷效果,与初始氟/砷浓度无关。

关 键 词:地下水  Al  C  Fe复合电极  电絮凝  同时除氟除砷

Simultaneous removal of fluoride and arsenic( V ) via Al/C/Fe combination electro-coagulation process
Qi Xueqian,Li Zetang,Zhou Yafang,Zhang Xu.Simultaneous removal of fluoride and arsenic( V ) via Al/C/Fe combination electro-coagulation process[J].Techniques and Equipment for Environmental Pollution Control,2014(2):525-530.
Authors:Qi Xueqian  Li Zetang  Zhou Yafang  Zhang Xu
Affiliation:1. School of Environment, Tsinghua University, Beijing 100084, China 2. Tieling Tianxin Public Utility Ltd. , Tieling 112000, China)
Abstract:In order to remove F- and As( V )ions from groundwater simultaneously, a system of Al/C/Fe combination electro-coagulation and a system of Al/C-Fe/C used in sequence were designed. Influencing factors of Al/C/Fe combination electro-coagulation were researched, and flocs produced in the combination electro-co- agulation were analyzed by SEM-EDX. The results showed that theAl/C/Fe combination system' s removal rates of F- and As( V ) ions are 1.43 times and 4.73 times of that of the system of Al/C-Fe/C used in sequence. When the current density of Al and Fe electrode is 0. 10 mA/cm2, the removal of F - and As( V ) ions is the best when the initial F/As( V ) concentrations are 4.0/1.0 mg/L,4.0//0 mg/L and 0/1.0 mg/L, so the best value of current density has no dependence on the initial F/As( V ) concentration.
Keywords:groundwater  Al/C/Fe combination  electro-coagulation  simultaneous removal of F-and As (V)
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