| 环氧树脂/粘土纳米复合材料的固化反应动力学 |
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| 引用本文： | 崔继文,王书红,李晓军,武冬梅,那辉,孟令锴. 环氧树脂/粘土纳米复合材料的固化反应动力学[J]. 吉林大学学报(理学版), 2008, 46(4): 774-778 |
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| 作者姓名： | 崔继文 王书红 李晓军 武冬梅 那辉 孟令锴 |
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| 作者单位： | 1. 佳木斯大学 化学与药学院, 黑龙江 佳木斯 154000； 2. 吉林大学 化学学院, 长春 130021；3. 佳木斯师范学校, 黑龙江 佳木斯 154000； 4. 牡丹江医学院 药学系, 黑龙江 佳木斯 153000 |
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| 基金项目： | 吉林省重大科技发展计划项目基金 , 佳木斯大学科研项目基金 |
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| 摘 要： | 用十六烷基三甲基溴化铵直接处理钙基蒙脱土(MMT), 使其层间距达到2.21 nm. 采用非等温差示扫描量热(DSC)法研究环氧树脂/粘土体系的固化反应动力学, 并用Kissinger方法求得其表观活化能ΔE=41.03 kJ/mol, 根据Crane理论计算得到反应级数为0.85, 确定了使用4,4′ 二氨基二苯醚二苯酮(BADK)作为固化剂的固化反应条件, 最后采用非等温DSC法研究了环氧树脂/粘土纳米复合材料的热性能. 结果表明, 纳米复合材料具有较高的玻璃化转变温度.
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| 关 键 词： | 钙基蒙脱土 环氧树脂 4 4′ 二氨基二苯醚二苯酮 X射线衍射 固化反应动力学 纳米复合材料 |
| 收稿时间： | 2007-11-13 |
Kinetics of Curing Reaction of Epoxy Resin/Montmorillonite Nanocomposites |
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| CUI Ji wen,WANG Shu hong,LI Xiao jun,WU Dong mei,NA Hui,MENG Ling kai. Kinetics of Curing Reaction of Epoxy Resin/Montmorillonite Nanocomposites[J]. Journal of Jilin University: Sci Ed, 2008, 46(4): 774-778 |
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| Authors: | CUI Ji wen WANG Shu hong LI Xiao jun WU Dong mei NA Hui MENG Ling kai |
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| Affiliation: | 1. College of Chemistry and Pharmacy, Jiamusi University, Jiamusi 154000, Heilongjiang Province, China;2. College of Chemistry, Jilin University, Changchun 130021, China; 3. Jiamusi Normal School, Jiamusi 154000, Heilongjiang Province, China; 4. Department of Pharmacy, Mudanjiang Medical University, Mudanjiang 153000, Heilongjiang Province, China |
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| Abstract: | Ca montmorillonite was directly modified with hexadecyl trimethyl ammonium bromide. The interlamellar spacing of the organophilic montmorillonite (O MMT), corresponding to the (001) plane peak reached 2.21 nm. The reaction process of the curing system (E 51/BADK/MMT) was studied by non isothermal DSC and carefully analyzed. Based on the Kissinger method, the apparent activation energy (ΔE) was calculated to be 41.03 kJ/mol. The reaction order(n=0.85) was calculated according to Crane theory. The curing reaction conditions with BADK as the curing reagent were found. At last, the thermal properties of epoxy resin/MMT nanocomposites were studied by non isothermal DSC. The experimental data indicate that Tg’s of nanocomposites are higher. |
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| Keywords: | Ca montmorillonite(MMT) epoxy resin(E 51) 4 4′ diaminodiphenylether diphenylketone (BADK) XRD curing reaction kinetic nanocomposite |
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