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天然气-煤共气化制备合成气热态模拟
引用本文:欧阳朝斌,段东平,郭占成,宋学平,于宪溥.天然气-煤共气化制备合成气热态模拟[J].化工学报,2005,56(10):1936-1941.
作者姓名:欧阳朝斌  段东平  郭占成  宋学平  于宪溥
作者单位:中国科学院过程工程研究所,北京 100080
基金项目:国家杰出青年科学基金项目(50225415);国家高技术研究发展计划项目(2002AA529090).
摘    要:天然气-煤共气化制备通用合成气技术是基于天然气蒸汽转化法和煤气化过程开发的新工艺,通过技术原理分析,可以直接制备出H2/CO在1.0~2.0之间可调的粗合成气.应用移动床反应器进行热态模拟实验,主要研究了不同操作参数对火焰区温度及合成气有效成分(H2+CO)和H2/CO的影响.结果表明:天然气与氧气在同一位置喷入反应器,控制喷吹参数H2O/CH4/O2以及流量,在气化炉炉温不低于1000 ℃的条件下,煤或焦炭中挥发分基本裂解,可以直接制备出H2/CO在1.0~2.0之间,有效成分大于90.0%,残留的CH4小于2.0%的粗合成气.

关 键 词:天然气    共气化  合成气  热态模拟  
文章编号:0438-1157(2005)10-1936-06
收稿时间:09 17 2004 12:00AM
修稿时间:2004-09-172004-11-24

Natural gas & coal co-gasification to produce synthesis gas in hot simulation
OUYANG Zhaobin,DUAN Dongping,GUO Zhancheng,SONG Xueping,YU Xianpu.Natural gas & coal co-gasification to produce synthesis gas in hot simulation[J].Journal of Chemical Industry and Engineering(China),2005,56(10):1936-1941.
Authors:OUYANG Zhaobin  DUAN Dongping  GUO Zhancheng  SONG Xueping  YU Xianpu
Affiliation:Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100080, China
Abstract:A new process, natural gas &; coal co-gasification for synthesis gas production,was developed by combining natural gas steam reforming and coal gasification process.The H2/CO ratio of crude synthesis gas could be controlled in the range of 1.0—2.0. Using a moving bed as reactor, coke and coal as the raw materials in the preliminary study of hot simulative experiments, the effects of blowing parameters H2O/CH4/O2 on the temperature in the flame zone and the H2/CO ratio of synthesis gas were investigated.Natural gas and oxygen were blown into the reactor at the same position to keep the temperature of reactor above 1000 ℃ and the blowing parameters H2O/CH4/O2 were adjusted to produce crude synthesis gas, in which the H2/CO ratio varied to the range of 1.0—2.0, the contents of active compounds (H2 and CO) were more than 90.0% and the residue methane was less than 2.0%.The concept of natural gas &; coal co-gasification process is correct and feasible.
Keywords:natural gas  coal  co-gasification  synthesis gas  hot simulation
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