| 一种新型钼磷酸盐杂多化合物(NH3CH2CH2NH3)7H2[NaMo12O30(PO4)2(HPO4)5(H2PO4)]·7H2O的合成和光谱研究 |
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| 引用本文： | 林郑忠,张汉辉,黄长沧,孙瑞卿,郑晓玲.一种新型钼磷酸盐杂多化合物(NH3CH2CH2NH3)7H2[NaMo12O30(PO4)2(HPO4)5(H2PO4)]·7H2O的合成和光谱研究[J].光谱学与光谱分析,2002,22(6):1048-1050. |
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| 作者姓名： | 林郑忠 张汉辉 黄长沧 孙瑞卿 郑晓玲 |
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| 作者单位： | 福州大学化学系结构化学国家重点实验室,福州,福建,350002 |
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| 基金项目： | 福建省教育厅资金 (JA0 0 1 37)，福建省科委基金项目 (2 0 0 0F0 0 2 ) |
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| 摘 要： | 本文采用水热反应条件 ,合成得到一种新型的含五价钼原子的杂多化合物 :(NH3CH2 CH2 NH3) 7H2NaMo1 2 O30 (PO4 ) 2 (HPO4 ) 5(H2 PO4 ) ]·7H2 O ,在晶体结构测定的基础上对其进行红外、拉曼和紫外 可见漫反射光谱研究。结果表明 :较长的Mo(Ⅴ )—O键键长和分子内大量的氢键造成化合物红外光谱特征的红移。
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| 关 键 词： | 水热合成 杂多化合物 钼 磷 |
| 文章编号： | 1000-0593(2002)06-1048-03 |
| 修稿时间： | 2001年10月14 |
Synthesis and Spectral Characterization of a New Molybdenum Phosphate Compound (NH3CH2CH2NH3)7H2[NaMo12O30(PO4)2(HPO4)5(H2PO4)]·7H2O |
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| Zheng-zhong Lin,Han-hui Zhang,Chang-cang Huang,Rui-qing Sun,Xiao-lin Zheng.Synthesis and Spectral Characterization of a New Molybdenum Phosphate Compound (NH3CH2CH2NH3)7H2[NaMo12O30(PO4)2(HPO4)5(H2PO4)]·7H2O[J].Spectroscopy and Spectral Analysis,2002,22(6):1048-1050. |
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| Authors: | Zheng-zhong Lin Han-hui Zhang Chang-cang Huang Rui-qing Sun Xiao-lin Zheng |
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| Affiliation: | Chemistry Department, Fuzhou University, State Key Laboratory of Structural Chemistry, Fuzhou 350002, China. |
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| Abstract: | The paper reports a new molybdenum phosphate (NH3CH2CH2NH3)7H2NaMo12O30(PO4)2(HPO4)5(H2PO4)].7H2O containing Mo(V) which is hydrothermally synthesized and spectrally characterized by FTIR, Raman and UV/Vis DRS. The result indicates long Mo(V)-O bonds and innumerable hydrogen bonds in compound cause the red shift of characteristic vibrations in IR spectrum of title compound. |
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| Keywords: | Hydrothermal synthesis Heteropoly compound Molybdenum Phosphor |
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