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一种新型吡唑啉衍生物荧光受体的合成及其离子识别性能
引用本文:罗杰伟,秦大斌,张仕禄.一种新型吡唑啉衍生物荧光受体的合成及其离子识别性能[J].化学研究,2013(5):444-447.
作者姓名:罗杰伟  秦大斌  张仕禄
作者单位:1. 川北医学院 基础医学院,四川 南充,637000
2. 西华师范大学 化学化工学院,四川 南充,637000
基金项目:四川省教育厅项目,川北医学院科研发展计划项目(CBY12-A-ZP17).
摘    要:以苯环为荧光基团合成了一种新的吡唑啉衍生物荧光受体;采用核磁共振光谱对目标化合物进行了结构表征,并利用荧光光谱法研究了其对常见阳离子的选择性识别.结果表明,合成的吡唑啉衍生物对Na+、H+、Fe3+、Cu2+具有良好的识别络合效果.

关 键 词:吡唑啉衍生物  荧光受体  合成  离子识别性能

Synthesis of a novel pyrazoline derivative as fluorescent receptor and evaluation of its ion-recognition capability
LUO Jiewei , QIN Dabin , ZHANG Shilu.Synthesis of a novel pyrazoline derivative as fluorescent receptor and evaluation of its ion-recognition capability[J].Chemical Research,2013(5):444-447.
Authors:LUO Jiewei  QIN Dabin  ZHANG Shilu
Affiliation:LUO Jie-wei;QIN Da-bin;ZHANG Shi-lu;School of Basic Medical Sciences,North Sichuan Medical College;College of Chemistry and Chemical Engineering,China West Normal University;
Abstract:A new pyrazoline derivative containing benzene ring as the fluorophore was synthe- sized as a fluorescent receptor. The structure of as-synthesized compound was characterized by nuclear magnetic resonance spectroscopy, and its selective recognition capability towards com- mon cations was studied by fluorescence spectrometry. Results indicate that as-synthesized pyrazoline derivative possesses good selective recognition capability towards anions such as Na+, H+, Fea+ andCu2+.
Keywords:pyrazoline derivative  fluorescent receptor  synthesis  ion recognition capability
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