| 国内催化合成草酸二丁酯的进展 |
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| 引用本文： | 俞善信,文瑞明. 国内催化合成草酸二丁酯的进展[J]. 塑料助剂, 2014, 0(5): 11-15 |
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| 作者姓名： | 俞善信 文瑞明 |
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| 作者单位： | 1. 湖南师范大学化学化工学院,长沙,410081
2. 湖南城市学院化学与环境工程系,益阳,413000 |
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| 基金项目： | 湖南省教育厅科研基金资助项目 |
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| 摘 要： | 评述了对甲苯磺酸,对甲苯磺酸铜,氨基磺酸,强酸性阳离子交换树脂,六水三氯化铁,固载三氯化铝,五水四氯化锡,硫酸铜,七水硫酸锌,氧化钐,一水硫酸氢钠,硫酸氢钾,固体超强酸,杂多酸和维生素C等催化剂催化合成草酸二丁酯的合成方法。认为固载对甲苯磺酸,对甲苯磺酸铜,氨基磺酸,强酸性阳离子交换树脂,活性碳固载四氯化锡,氧化钐,一水硫酸氢钠,硫酸氢钾,固体超强酸,杂多酸和维生素C是合成草酸二丁酯的良好催化剂。微波辐射是有机合成的良好方法。
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| 关 键 词： | 草酸二丁酯 合成 催化剂 |
Progress on Catalytic Synthesis of Dibutyl Oxalate in Domestic |
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| Yu Shanxin,Wen Ruiming. Progress on Catalytic Synthesis of Dibutyl Oxalate in Domestic[J]. Plastic Additives, 2014, 0(5): 11-15 |
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| Authors: | Yu Shanxin Wen Ruiming |
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| Affiliation: | Yu Shanxin,Wen Ruiming (1. College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha,410081; 2. Department of Chemistry and Environmentally Engineering, Hunan City University, Yiyang,413000) |
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| Abstract: | The catalytic synthesis of dibutyl oxalate with p-toluene sulfonic acid,copper p-toluene sulfonate,amino sulfonic acid,strong-acid positive ion exchange resin,ferric chloride hexahydrate,supper aluminium chloride,stannic chloride pentahydrate,copper sulfate,zine sulfate sevenhydrate,Sm2O3,sodium bisulfate monohydrate,potassium bisulfate,solid super acid,heteropoly acid and vitamin C were reviewed.The solid supported p-toluene sulfonic acid,copper p-toluene sulfonate,amino sulfonic acid,strong-acid positive ion exchang resin,supported stannic chloride,Sm2O3,sodium bisulfate monohydrate,potassium bisulfate,solid super acid,heteropoly acid and vitamin C are more suitable for catalytic synthesis of dibutyl oxalate.Microwave irradiation are a good method of organic synthesis. |
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| Keywords: | dibutyl oxalate synthesis catalyst |
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