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金银铂族元素成矿机理的新探索
引用本文:郑大中,郑若锋. 金银铂族元素成矿机理的新探索[J]. 四川地质学报, 2002, 22(4): 210-218
作者姓名:郑大中  郑若锋
作者单位:成都综合岩矿测试中心,四川成都,610081
摘    要:通过对金、银、铂族元素的氢化物,羧基化合物理化性质,贵金属矿物主要和次要化学成分,贵金属矿物的共伴生矿物组合,有关矿物流体包裹体化学成分,类地行星概况,生产实验等相关问题的讨论,认为金、银、铂族元素主要呈单质及其合金氢化物,单质羧基化合物,单质羧基氢化物迁移的。它们随岩浆,热液,热气迁至地壳浅部,由于减压,降温,氧逸度显著加大,Eh、Ph值发生变化,H2,CO逃逸,氧化,形成贵金属的单质及合金矿物,有的还能与硫,硫化氢作用形成贵金属的硫化矿物和硫盐矿物。

关 键 词:金 银 铂族元素 成矿机理 贵金属氢化物 贵金属合金氢化物 迁移形式 流体包裹体
文章编号:1006-0995(2002)04-0210-09

A New Study of Genetic Mechanism for Au, Ag and PGE Mineralizations
Zheng Dazhong Zheng Ruofeng. A New Study of Genetic Mechanism for Au, Ag and PGE Mineralizations[J]. Acta Geologica Sichuan, 2002, 22(4): 210-218
Authors:Zheng Dazhong Zheng Ruofeng
Abstract:An analysis of physical and chemical properties of hydride and carbonyl compounds of Au,Ag and PGE,major and secondary chemical compositions and paragenetic ssociation of precious metal minerals,chemical composition of fluid inclusions,composition of terrestrial planet and related experimental results indicate Au,Ag and PGE were migrated to upper level in crust as elements and their hydrides,carbonyl compounds and carbonyl hydrides with mgmatic,hydrothermal and gas-liquid fluids and precipitated as metals and alloys,sulfides and sulfosalts by decrease in pressure and temperature and increase in oxygen fugacity and change in Eh and pH values and so on.
Keywords:precious metal hydride  precious alloy hydride  precious carbonyl compound  migrated form  ore-forming mechanism
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