| 双核钴配合物(RC_2R′)CO_2(CO)_6_n[P(OEt)_3]_n的合成与结构 |
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| 引用本文： | 孟庆金,孙守恒,游效曾.双核钴配合物(RC_2R′)CO_2(CO)_6_n[P(OEt)_3]_n的合成与结构[J].有机化学,1990(2). |
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| 作者姓名： | 孟庆金 孙守恒 游效曾 |
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| 作者单位： | 南京大学配位化学研究所，南京大学配位化学研究所，南京大学配位化学研究所 江苏，南京，210008，江苏，南京，210008，江苏，南京，210008 |
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| 基金项目： | 国家自然科学基金重大项目资助课题 |
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| 摘 要： | PR_3可取代(RC_2R′)Co_2(CO)_6中的CO生成相应的取代配合物(RC_2R′)CO_2(CO)_(6-n)(PR_3)n: (RC_2R′)Co_2(CO)_6 +nPR_3→ (RC_2R′)Co_2(CO)_(6-n)(PR_3)n已经利用此反应合成了一系列PR_3取代配合物,但P(OEt)_3的取代配合物则未见报
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| 关 键 词： | 双核钴配合物 取代反应 合成 结构 |
Synthesis and Structure of Dinuclear Cobalt Complexes (RC_2 R') Co_2 (CO)_(6-n) [P(OEt)_3]_n |
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| MENG Qing-Jin,SUN Shou-Heng,YOU Xiao-Zeng Coordination Chemistry Institute,Nanjing University, Nanjing,Jiangsu.Synthesis and Structure of Dinuclear Cobalt Complexes (RC_2 R'''') Co_2 (CO)_(6-n) [P(OEt)_3]_n[J].Chinese Journal of Organic Chemistry,1990(2). |
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| Authors: | MENG Qing-Jin SUN Shou-Heng YOU Xiao-Zeng Coordination Chemistry Institute Nanjing University Nanjing Jiangsu |
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| Affiliation: | MENG Qing-Jin,SUN Shou-Heng,YOU Xiao-Zeng Coordination Chemistry Institute,Nanjing University,210008 Nanjing,Jiangsu |
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| Abstract: | Ten new complexes with formula(RC_2 R') Co_2(CO)_(6-n) P(OEt)_3]_n(n=1, 2) havebeen synthesized from P(OEt)_3 nucleophilic substituting CO in (RC_2R') Co_2(CO)_?. The reac-tion of P(OEt)_3 substituting CO in the complexes has been discussed from the synthesizedcondition of four mono-substituted complexes. IR. UV and ~1H NMR spectra of complexeshave been studied and the structure information of these complexes have been obtained. |
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| Keywords: | dinuclear cobalt complex substituting reaction synthesis structure |
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