Reliability of 100 nm silicon nitride capacitors in an InP HEMT MMIC process

A reliability study has been conducted on capacitors made with 100 nm of silicon nitride, in an InP HEMT MMIC fabrication process. Special wafers were fabricated, containing 1482 200 × 200 μm² capacitors each, and these were probed automatically. They were subject to ramped-voltage stress and the breakdown voltages recorded. On a typical wafer the vast majority of the breakdown voltages are between 50 and 90 V. In addition, IV curves were measured on a small number of specimens from 0 V up to breakdown. This was done in two regimes: above 25 V with a conventional setup, and below 25 V with an ultra-low-current measurement system. These were done at 25 and 175 °C above 25 V, and at 25 °C only below 25 V. The data were fitted well with a model for the conductivity, consisting of ohmic conduction at low voltages and Frenkel–Poole conduction at high voltages. Parameters of the fits included thermal activation energies, the voltage acceleration factor in the Frenkel–Poole model, and d_eff, the effective thickness of the dielectric at the thinnest point. Analysis invoked the time-dependent dielectric breakdown model, which provides the time to failure as a function of the d_eff, while d_eff can be found from the ramped-voltage measurements. From the 10 wafers that have been probed so far, the mean of the distribution of failure times (at 1.5 V, 40 °C) is above 5 × 10⁷ h, and the distribution becomes insignificant below 2 × 10⁶ h. Further, the probability of failure in 10 years at 1.5 V, 40 °C is much less than 1 in 14,600. This indicates that 100 nm silicon nitride capacitors in this technology have good reliability.