Oxoneptunium(v) as part of the framework of a polyoxometalate |
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| Authors: | Copping Roy Gaunt Andrew J May Iain Sharrad Clint A Collison David Helliwell Madeleine Fox O Danny Jones Chris J |
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| Affiliation: | Centre for Radiochemistry Research, School of Chemistry, University of Manchester, Oxford Road, Manchester, UKM13 9PL. |
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| Abstract: | (NH4)14Na4[(Np3W4O15)(H2O)3(BiW9O33)3].62H2O (1) and (NH4)14.5Na3.5[(Np3W4O15)(H2O)3(SbW9O33)3].40.5H2O (2) each contain three neptunyl(v) moieties encapsulated within heteropolyoxotungstate frameworks in which axial {NpO2}+ oxygens form one face of a WO6 octahedron. |
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