一维链状镍配位聚合物{[Ni(4,4′-bipy)(2,4,6-TMBA)2(H2O)2]·(CH3OH)}n的合成、晶体结构及电化学性质 |
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作者姓名: | 杨颖群 李昶红 李 薇 匡云飞 |
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作者单位: | 衡阳师范学院化学与材料科学系,衡阳 421008,湖南工学院化学化工系,衡阳 421002,衡阳师范学院化学与材料科学系,衡阳 421008,衡阳师范学院化学与材料科学系,衡阳 421008 |
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基金项目: | 湖南省重点学科建设资助项目,衡阳师范学院青年项目(No.2003C16) |
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摘 要: | One dimensional chain nickel(Ⅱ) coordination polymer has been synthesized with 2,4,6-trimethylbenz-oic acid, 4,4′-bipyridine and nickel perchlorate anhydrous, and characterized in the solvent mixture of water and methyl-alcohol. Crystal data for this complex: monoclinic, space group C2/c, a=2.154 7(7) nm, b=1.131 9(2) nm, c=1.655 7(8) nm, β=129.66(3)°, V=3.108 7(19) nm3, Dc=1.370 g·cm-3, Z=4, F(000)=1 360, final GooF=1.042, R1=0.034 4, wR2=0.078 7. The crystal structure shows that the nickel ion is coordinated with two nitrogen atoms of two 4,4′-bipyridine molecules and four oxygen atoms from two 2,4,6-trimethylbenzoic acid molecules and two water molecules, respectively, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 649415.
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关 键 词: | 镍(Ⅱ)配合物 合成 晶体结构 电化学性质 |
文章编号: | 1001-4861(2007)10-1815-04 |
修稿时间: | 2007-06-18 |
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