Delayed geochemical hazard: Concept, digital model and case study

Delayed Geochemical Hazard (DGH briefly) presents the whole process of a kind of serious ecological and environmental hazard caused by sudden reactivation and sharp release of long-term accumulated pollutant from stable species to active ones in soil or sediment system due to the change of physical-chemical conditions (such as temperature, pH, Eh, moisture, the concentrations of organic matters, etc.) or the decrease of environment capacity. The characteristics of DGH are discussed. The process of a typical DGH can be expressed as a nonlinear polynomial. The points where the derivative functions of the first and second orders of the polynomial reach zero, minimum and maximum are keys for risk assessment and harzard pridication.The process and mechanism of the hazard is due to the transform of pollutant among different species principally. The concepts of "total releasable content of pollutant", TRCP, and "total concentration of active specie", TCAS, are necessarily defined to describe the mechanism of DGH. The possibility of the temporal and spatial propagation is discussed. Case study shows that there exists a transform mechanism of "gradual release" and "chain reaction" among the species of the exchangeable and the bounds to carbonate, iron and manganese oxides and organic matter, thus causing the delayed geochemical hazard.     

基于公平性的水环境容量分配研究——以沱江流域为例

公平与效益是容量分配的两个重要原则.在我国目前采用的水环境容量无偿分配方式下,公平原则是需遵循的首要原则,在公平的基础上追求效益.以沱江流域为对象,综合考虑涉及区域的社会、经济、自然等客观因素,筛选指标确定系数对流域容量进行分配.应用经济学中衡量收入公平的基尼系数概念,对分配结果的公平性进行评估,给出综合体现社会性、经济性和历史性的水环境容量分配方案.     

Analysis on Bearing Capacity of Tunnel-Type Anchorage of a Long-Span Suspension Bridge

INTRODUCTION Tunnel typeanchoragehasobviousadvantages inbearingcapacityversusinvestment(LiuandHu,1996).However,itisrarelyusedinapracticalpro jectbecauseofitsrequirementofgoodrockcondi tions.Siduhebridge(Fig.1),whichliesintheBa dongmountainsinthewestplatea…     

水流挟沙力分析与探讨

水流挟沙力是悬沙输运计算中非常重要的问题之一,其计算形式常采用基于重力理论的经验和半经验公式.本文针对目前广泛采用的2种挟沙力关系式,选用4组实验水槽数据和2组天然河道实测资料分别讨论其关联性.结果表明,不论指数m在其取值范围内取何值,2个表达式皆存在一定的函数关联性.且当指数m取1和2/3时,直接表现出很强的线性关联.在挟沙力计算中采用流速的平方关系式,物理意义清晰,形式简单.在实际应用时,适当选取系数,挟沙力采用形式简单的平方关系式是完全可行的.     

考虑高振型影响的结构层间位移能力谱分析方法

工程界普遍采用的能力谱分析方法是建立在结构单自由度简化假设基础上，利用结构基本振型来进行能力分析。虽然此简化假设可以为工程界提供一种简便的分析方法，但从其分析效果来看，简化方法并不能很好地反映结构真实地震反应。高振型对结构局部变形的影响在分析结构动力反应特性中是很重要的因素，不应忽略掉。基于上述对现有能力谱分析方法不足之处的考虑，从提高结构能力谱分析方法的准确性出发，本文在Chopra能力谱分析方法的基础之上，根据我国振型分解反应谱思想，在能力谱分析方法中引入了结构高振型的影响分析，并提出了考虑结构高振型影响的结构层间位移能力谱分析方法的一般步骤。通过平面框架结构体系的算例分析，说明上述推荐方法在改进能力谱分析精度上的有效性。     

人地关系的地图表现──开县土地人口容量图编制过程

运用地图的表现手法,研究土地和人口之间的复合关系,设计出新的人地关系图种土地人口容量图,阐述了土地人口容量图编制原则、方法和特点．     

Partitioning of heavy metals on soil samples from column tests

In this study, column tests were used to determine the retention capability of three types of estuarine alluvia collected adjacent to landfill sites in South Wales. Selective sequential extraction (SSE) was used to study the retention mechanisms of heavy metals in the soil columns obtained from leaching experiments. Acid digestion was later used to check the validity of the SSE results. Breakthrough curves show good retention of heavy metal ions (Pb, Cu, and Zn) by all soils, where almost 99% of heavy metals were retained with the C_e/C_o values in the order of 10⁻³. The retention strength of these soils was observed to be constant up to five pore volumes (PV). This corresponds with the pH of the effluents and pore water of soil slices, which also show good buffering capacity against very acidic leachate up to 5PV. The heavy metal extraction profiles from SSE show very similar trends with the retention profiles from the leaching experiments, where heavy metals were retained mainly at the top part where the leachate entered the column. SSE indicates qualitatively that heavy metals precipitated with carbonates and amorphous materials (oxides/hydroxides) are higher than heavy metal retention via exchangeable mechanisms. The mass balance calculation gives range of deviation of 1–16% of the total soil extraction. The distribution of the heavy metals with various soil constituents are ranked in the following order: Carbonates>Amorphous oxides hydroxides>Organic matter>Exchangeable phases.