Some breakage characteristics of ultra-fine wet grinding with a centrifugal mill

A centrifugal mill is a high-power intensity media mill that can be used for ultra-fine grinding, employing centrifugal forces generated by gyration of the axis of the mill tube in a circle. The mill charge motion is quite different depending on the ratio of the gyration diameter to the mill diameter (G / D ratio), varying from a motion similar to that of a conventional tumbling media mill to that of a vibration mill. In this study, a centrifugal mill was constructed with an arrangement where the gyration diameter could be readily adjusted. The batch grinding characteristics of three different minerals (limestone, talc and illite) in water with dispersing agent were investigated at various G / D ratios. It was found that the optimum G / D ratio in terms of the specific energy consumption to give a desired fineness of product was different for the three minerals. This was due to their different reactions to the breakage mechanisms provided by the mill charge motion at varying G / D ratios. The size distributions became progressively narrower at increased grinding times, and particles finer than about 0.1 μm were not detected even for prolonged grinding times. Measurement of specific surface areas indicated that this was not due to an artifact of the size measurements by laser diffractometry. This implies that there is a limitation in which particles finer than 0.1 μm are not produced under the conditions tested in this type of mill, but further investigation is needed for experimental verification of this limit of comminution.     

类脂化合物单体碳稳定同位素在古气候环境研究中的意义

类脂化合物极大地扩展了全球变化研究的深度，尤其是单体碳稳定同位素技术在古气候、古环境重建上有着重要作用。基于近些年来国内外的最新研究成果，就类脂化合物单体碳同位素在古气候环境方面的应用研究进行了较为全面的评述。已有研究表明利用类脂化合物单体碳同位素组成可以追溯到海洋和湖泊环境中陆源有机质的物源，其母源区历史时期 C3、C4植被的变迁以及区域性的古气候、古环境重建。     

The role of sediment specific gravity and availability on cluster evolution

The objective of this experimental study was to account for the role of sediment availability and specific gravity on cluster formation and cluster geometric characteristics (spacing and size). To isolate the effects of sediment availability and specific gravity on cluster evolution, mono‐sized spheres were used to simulate the cluster evolutionary cycle. Overall, twelve experimental runs were carried out in the laboratory flume. Six of these tests were performed by using glass spheres (specific gravity, SG = 2·58) and the other six by employing an equal combination of glass and Teflon spheres (SG = 2·12) of the same diameter to evaluate the role of specific gravity on cluster evolution. The three sediment availability conditions that were investigated here simulated isolated gravel elements, pool–riffle sequences and densely packed gravel‐bed. An advanced image analysis technique was employed to track the evolution of cluster microforms and provide quantitative information about the size and shape of clusters and the number of clusters per unit area. The results of this study showed that: (1) sediment availability affects the architecture and size of cluster microforms; and (2) clusters consisting of mono‐sized sediments start disintegrating at twice the incipient conditions. By performing complementary tests for the isolated gravel elements case, it was found that the evolutionary cycle of individual clusters could be described as follows, in order of increasing stress: no cluster→two particle cluster→comet→triangle→rhomboid→break up. Copyright © 2003 John Wiley & Sons, Ltd.     

水中氯代烃单体碳同位素分析中预富集方法进展

高精度准确测定氯代烃单体碳同位素对示踪污染物来源,了解污染物的生物降解过程具有重要意义。在环境转化过程中,有机污染物的同位素组成可能是稳定不变的,也有可能发生改变。若污染物的同位素组成在迁移转化过程中不变,根据其同位素组成可以示踪污染物的来源;若同位素组成变化,根据同位素分馏结果,可以评价环境中有机污染物降解发生的可能性和程度。本文综述了固相微萃取、静态顶空进样、吹扫-捕集、多级串联技术等前处理方法与气相色谱-燃烧-同位素比值质谱仪(GC-C-IRMS)联用分析水中氯代烃单体碳同位素的研究进展,比较了分析方法的优缺点。液-液萃取较少用于水中氯代烃的单体同位素分析。静态顶空进样、固相微萃取、吹扫-捕集都是无溶剂富集技术,与GC-C-IRMS联用分析水中氯代烃单体同位素过程中不存在或存在小且恒定的可校正的同位素分馏,分析精度一般优于1‰,没有二次污染,降低了杂质干扰,提高了GC-C-IRMS的分辨率和分析精度,降低了检测限。从静态顶空进样、固相微萃取、吹扫-捕集,到多级串联等技术与GC-C-IRMS联用分析水中氯代烃单体同位素比值,检测限逐渐降低。目前,吹扫-捕集-GC-C-IRMS在分析水中氯代烃中应用最广泛,重现性好、检测限低。针内微萃取、管内微萃取、搅动棒吸附萃取和顶空进样吸附萃取等前处理方法与GC-C-IRMS仪联用具有一定的应用前景。     

鄂尔多斯盆地煤储层低温氮等温吸附特征分析

利用美国Micromritcs ASAP 2000自动等温吸附仪,测试了鄂尔多斯盆地煤储层孔隙特征。在测试数据分析的基础上,确定了等温吸附和脱附曲线3种类型:第1类属孔结构是具有平行权构成的狭缝毛细孔型;第2类为发育一端尖灭的不平行的裂隙型;第3类属“墨水瓶”型孔。总结了鄂尔多斯盆地煤储层几种常见的比表面积分布曲线及累计孔体积分布曲线模型。     

古代生物分子在第四纪研究中的应用

从第四纪化石和沉积物中获得的古代生物分子为第四纪研究者提供了丰富和独特的有关古代生物、遗传和古环境信息的定量和高分辨率的数据.过去10多年的研究证实来自第四纪材料中的各种古代生物分子的分离、鉴定和应用的能力在不断增加.文章总结了古代生物分子在第四纪研究中的最新进展,主要包括以下几个方面的内容:1)不同类型的古代生物分子在地质体中的保存和降解;2)古DNA和古蛋白序列中的生物遗传学信息;3)单体分子同位素与第四纪古环境和古气候研究;4)建于古代生物分子水平上的第四纪年代学.作者预见对第四纪地层中的原位和分散保存的古代生物分子的研究将在广度上以多分子综合研究而深度上与单体分子同位素技术相结合,为第四纪科学家们提供大量解决地质学和演化生物学问题的高精度数据.随着地球化学和分子生物学技术的不断改进以及人们对古代生物分子的降解过程和机制的进一步理解,对古代生物分子的研究无疑将进一步促进和推动第四纪科学研究的发展.     

放养密度对大杂交鲟生长性能的影响及生理应答机制

为探讨放养密度对鱼类生长及生理应答机制的影响规律和作用,作者以大规格大杂交鲟(达氏鳇(Huso dauricus)♀×施氏鲟(Acipenser schrenckii)♂)为实验材料,研究了平均初始体质量约为243 g/尾,放养密度分别为6(SD1组)、9(SD2组)、12(SD3组)、15 kg/m3(SD4组)条件下,不同放养密度处理70 d后的实验鱼生长性能变化及生理应答机制。结果显示,放养密度对大杂交鲟肥满度影响不显著,SD2组鱼类具有最大的特定生长率和生长效率,随着放养密度增加,日增质量显著降低(P0.05),特定生长率和生长效率下降。测定了血液甲状腺素(T4)、三碘甲腺原氨酸(T3)和皮质醇水平变化,发现放养密度能引起大杂交鲟3个血液生理指标发生显著改变;随着养殖时间推移,T3和皮质醇浓度显著升高,T4浓度显著下降(P0.05)。这些结果说明神经内分泌活动的变化引起大杂交鲟血液生理指标变化,进而影响实验鱼生长性能。因此,在该养殖条件下推荐的养殖密度为9 kg/m3。     

特定折扣率的二度价格歧视研究

研究基于垄断厂商收益最大化的特定折扣率的定价问题,给出解的具体表达式,同时解决原有文献中需求函数为非线性函数时,最优固定折扣率的解的问题。     

内蒙古荒漠草原沙生针茅(Stipa glareosa)、碱韭(Allium polyrhizum)和骆驼蓬(Peganum harmala)叶形态性状对土壤水氮耦合的响应

研究降水和氮沉降对荒漠草原植物叶形态性状的影响,对于预测未来全球变化下荒漠草原植物的生态适应具有重要意义.对增减雨(±50％)和氮添加(10 g·m-2.a-1)及其交互作用对乌拉特荒漠草原区优势植物叶形态性状的影响研究结果表明:(1)沙生针茅(Stipa glareosa)、碱韭(Allium polyrhizum)...