Influence of Reaction Parameters on the Hydrogenolysis of Hydroxymatairesinol Over Carbon Nanofibre Supported Palladium Catalysts

The density functional theory (DFT/B3LYP) calculations were applied to investigate the interaction of a Pt₆ particle with the ZSM-5 zeolite framework. The electronic structure of the metal particle is strongly affected by the interaction with basic framework oxygens and acid sites of the zeolite support. Adsorption on basic sites (E_ads = 6 kcal/mol) favors the formation of the electron enriched metal cluster. Interaction of the platinum cluster with the acid site characterized by stabilization energy of 47 kcal/mol results in oxidation of the metal particle and suppression of Brønsted acidity of the support. The hypothesis is put forward that the oxidized platinum particle can function as an active site for the alkane isomerisation on platinum supported high silica zeolites.     

一种前馈型全摆幅恒跨导准恒增益CMOS运放设计

设计了一种适合在低电源电压下工作的前馈型输入级放大结构，在全摆幅的动态工作范围内，输入级跨导保持不变，采用负载电流补偿以保证增益近似恒定，输出采用前馈型AB类输结构，实现全摆幅输出。     

滑移线场近似作图法的原理

给出了滑移线场近似作图法的原理、证明以及近似滑移线场的特点，为进一步利用计算机求解应力分布和变形规律，尤其是为近似滑移线的计算机绘制奠定了基础．     

Rectilinear steiner tree heuristics and minimum spanning tree algorithms using geographic nearest neighbors

We study the application of the geographic nearest neighbor approach to two problems. The first problem is the construction of an approximately minimum length rectilinear Steiner tree for a set ofn points in the plane. For this problem, we introduce a variation of a subgraph of sizeO(n) used by YaO [31] for constructing minimum spanning trees. Using this subgraph, we improve the running times of the heuristics discussed by Bern [6] fromO(n ² log n) toO(n log² n). The second problem is the construction of a rectilinear minimum spanning tree for a set ofn noncrossing line segments in the plane. We present an optimalO(n logn) algorithm for this problem. The rectilinear minimum spanning tree for a set of points can thus be computed optimally without using the Voronoi diagram. This algorithm can also be extended to obtain a rectilinear minimum spanning tree for a set of nonintersecting simple polygons.The results in this paper are a part of Y. C. Yee's Ph.D. thesis done at SUNY at Albany. He was supported in part by NSF Grants IRI-8703430 and CCR-8805782. S. S. Ravi was supported in part by NSF Grants DCI-86-03318 and CCR-89-05296.     

Targeting optimum resource allocation using reverse problem formulations and property clustering techniques

Decoupling the constitutive equations from the balance and constraint equations allows for reformulating a conventional forward problem into two reverse problems. The first reverse problem is the reverse of a simulation problem, where the process model is solved in terms of the constitutive (synthesis/design) variables instead of the process variables, thus providing the synthesis/design targets. The second reverse problem (reverse property prediction) solves the constitutive equations to identify unit operations, operating conditions and/or products by matching the synthesis/design targets. Visualization of the problem is achieved by employing recently developed property clustering techniques, which allows a high-dimensional problem to be visualized in two or three dimensions. The clusters by definition satisfy intra-stream and inter-stream conservation through linear “mixing” rules, which allows for the development of consistent additive rules along with their ternary representation.     

RLL码的计算机辅助设计

本文着重讨论计算机辅助设计RLL码的具体实现问题.该过程首先根据RLL码两个参数d,k确定一个编码率p/q,然后构造出RLL码的高阶状态转换-输出符号矩阵并求相应的近似特征向量.最后通过状态分裂和状态归并过程,即可得到一个满足d,k约束的编码输出表.其中状态转换-输出符号矩阵为实现计算机辅助设计RLL码提供了有效的数据结构,而且要优化RLL码编码器,就必须有选择地进行状态分裂.     

关于Grünwald型多项式算子的线性组合

研究了Grünwald型多项式算子Hn(f;x,r)对f(x)∈Cj[-1,1],1≤j≤r的逼近阶,在连续状态下给出了点态的逼近阶.     

Algorithm for finding all k nearest neighbors

A very simple algorithm for computing all k nearest neighbors in 2-D is presented. The method does not rely on complicated forms of tessellation, it only requires simple data binning for fast range searching. Its applications range from scattered data interpolation to reverse engineering.     

Mathematical modelling of a reverse flow reactor with catalytic surface dynamics

This paper studies a system of partial differential equations modelling the behaviour of a reverse flow reactor. For the parameters appropriate for the oxidation of ammonia on a Pt/Al₂O₃ catalyst in a typical laboratory set-up, the reactor may be split into regions where approximate formulas that determine its behaviour are deduced. Numerical calculations are presented and can be used to compare with the analytical formulas. The physical insight gained from the asymptotic analysis suggests a new switching strategy which is the subject of numerical experiments. The switching strategy is found to be efficient at minimising the ammonia exiting the reactor after reversal.     

合成彩色立方氧化锆的宝石学特征

市场上出现的紫色、浅紫色、浅黄色、粉红色、酒黄色、黄褐色、红色人造立方氧化锆均为亚金刚光泽, 火彩明显; 密度为5.99～6.34 g/cm3, 相对硬度为8～9; 除粉红色者表现出非均质性和弱多色性且内含大量定向排列的白色脱溶物外, 其余的为均质性, 内部洁净; 不同颜色的立方氧化锆的吸收光谱、紫外荧光以及滤色镜下的变色情况均存在差异; 浅紫色立方氧化锆的吸收光谱特征表明它是Nd致色. 能谱分析结果表明: 彩色立方氧化锆的常见元素有Zr, Y, P, Hf, Ca等; Er, Ce, Fe分别是粉红色、红色、酒黄色立方氧化锆的致色元素; 当Y2O3的摩尔分数大于或近于7%时, 立方氧化锆为立方面心结构且内部洁净; 当Y2O3的摩尔分数小于5%时, 立方氧化锆表现为非均质性且内含大量定向分布的白色脱溶物. 用拉尔森改写的格拉斯顿-代尔公式计算其近似折射率为2.12～2.19.