45钢表面超音速电弧喷涂Ti-Al涂层的组织与性能研究

采用自行开发研制的超音速电弧喷设备，在45钢表面制成了钛铝合金复合涂层。并利用金相显微镜、X射线衍射仪、扫描电镜、电子探针，对涂层的成分、相结构、显微组织及其结合强度、显微硬度进行了研究。结果表明，利用超音速电弧喷涂设备，可以在45钢表面形成 度高、孔隙率低，结合强度较好和硬度高的Ti-Al合金涂层。     

Ti-45Al-10Nb合金的高温氧化行为

研究了Ti—45A1—10Nb(原子分数，％)合金在800-960℃在氧气和空气中的氧化行为．结果表明，该合金具有较好的高温抗氧化性能，其氧化增重速率与铁基耐热不锈钢相似或略优．与Ti—50A1合金相反，Ti-45A1-10Nb合金在空气中的氧化增重速率明显低于在纯氧中的氧化增重速率．X射线衍射与能谱分析表明，Ti-45Al一10Nb合金在氧气中的氧化产物主要有TiO2和Al2O3，但在空气中的氧化产物中有TiN相．这是降低氧化速率的主要原因，同时，合金元素Nb稳定了氧化层中的TiN相，因而提高了合金在空气中的抗氧化性能．     

CCUS in a net-zero U.S. power sector: Policy design,rates, and project finance

Carbon capture utilization and storage is an important technology option to rapidly and profoundly decarbonize the power sector, but will not deploy without substantial incentives or regulation. Assessment of U.S. policy options reveals that current incentives only partially close the finance gap and are most sensitive to fuel type and ownership structure. Recent proposed legislation would in some designs attract private investment for many projects, leading to widespread deployment of CCUS in the power sector. Additional constraints and concerns (including technology options and presence of CO₂ infrastructure) could play an important secondary role. This study discusses the specific US incentive policies that can provide investors and lenders with net cash flows that are adequate to attract private capital to CCUS power projects in the US.     

Surface performance of workpieces processed by electrical discharge machining in gas

The surface performance of workpieces processed by electrical discharge machining in gas(dry EDM)was studied in this paper.Firstly,the composition,micro hardness and recast layer of electrical discharge machined(EDMed)surface of 45 carbon steels in air were investigated through different test analysis methods.The results show that the workpiece surface EDMed in air contains a certain quantity of oxide,and oxidation occurs on the workpiece surface.Compared with the surface of workpieces processed in kerosene,fewer cracks exist on the dry EDMed workpiece surface,and the surface recast layer is thinner than that obtained by conventional EDM.The micro hardness of workpieces machined by dry EDM method is lower than that machined in kerosene,and higher than that of the matrix.In addition,experiments were conducted on the surface wear resistance of workpieces processed in air and kerosene using copper electrode and titanium alloy electrode.The results indicate that the surface wear resistance of workpieces processed in air can be improved,and it is related with tool material and dielectric.     

An EXAFS study of the Mo/TiO2 hydrodesulphurization catalysis

In-situ EXAFS studies of sulphided Mo/TiO₂ catalysts have shown that at low Mo loadings (2–4 wt%), an active species with a short Mo-S distance of 2.25 Å is formed, while on Mo/TiO₂ with high Mo loadings as well as on Mo/-Al₂O₃, bulk MoS₂ (Mo-S, 2.42 Å) is formed. The species with the short Mo-S distance has Mo in an oxidation state close to 6 + and is likely to result from the sulphidation of the tetrahedral molybdate species present in the oxidic precursor at low Mo loadings. The calcination temperature of the oxidic precursor appears crucial, a high calcination temperature of 973 K favouring the formation of MoS₃ on sulphidation, and a low calcination temperature of 623 K favouring MoS₂.Contribution No. 790 from the Solid State and Structural Chemistry Unit.     

45钢的离子氮碳共渗-离子渗氧复合处理

研究了45钢离子氮碳共渗-离子渗氧复合处理工艺。试验表明，45钢经离子氮碳共渗-离子渗氧复合处理后，表层可获得化合物和氧化物的复合层，该复合处理可以明显提高45钢的耐磨性。     

氮碳共渗钢的拉伸特性

本文对45钢氮—碳共渗不同冷却方式的拉伸特性进行了研究。试验得到一种新的锯齿状拉伸曲线和与之相对应的三区域断口特征。拉伸曲线和断口特征与冷却方式有关,并对此进行了分析。     

硬质合金与钢的热等静压扩散连接

研究了硬质合金ＹＧ１５Ｃ与４５~＃碳钢的热等静压扩散连接工艺，探讨厂连接温度、压力、保温保压时间、中间夹层及其厚度和连接残余热应力等对接合强度的影响．结果表明：热等静压扩散连接强度强烈依赖于连接温度，受控于连接后因ＹＧ１５Ｃ与４５~＃钢热膨胀失配而产生的残余热应力。采用镍箔作中间夹层可有效地减小残余热应力对连接的影响，显著提高接合强度．     

表面感应淬火对45钢滚动磨损特性的影响

针对传统热处理后45钢耐磨性较低的缺点,研究了正火 表面感应淬火热处理后45钢相对ZG31Mn2Si摩擦副的滚动磨损特性和磨损机理.测试了试验载荷、材料硬度与磨损失重的关系,采用扫描电镜分析了感应淬火热处理后不同硬度45钢的磨损形貌及变化规律.结果表明:当载荷恒定,磨料硬度Ha大于被磨材料45钢硬度Hm时,45钢随着感应淬火后自身硬度的提高,耐磨性明显提高,为硬磨料磨损;Ha＜Hm时,随着材料硬度的提高,磨损量变化很小,为软磨料磨损;其滚动磨损机理随着表面感应淬火后硬度的升高由塑变磨损转变为犁沟磨损.     

Quantifying requirements volatility effects

In an organization operating in the bancassurance sector we identified a low-risk IT subportfolio of 84 IT projects comprising together 16,500 function points, each project varying in size and duration, for which we were able to quantify its requirements volatility. This representative portfolio stems from a much larger portfolio of IT projects. We calculated the volatility from the function point countings that were available to us. These figures were aggregated into a requirements volatility benchmark. We found that maximum requirements volatility rates depend on size and duration, which refutes currently known industrial averages. For instance, a monthly growth rate of 5% is considered a critical failure factor, but in our low-risk portfolio we found more than 21% of successful projects with a volatility larger than 5%. We proposed a mathematical model taking size and duration into account that provides a maximum healthy volatility rate that is more in line with the reality of low-risk IT portfolios. Based on the model, we proposed a tolerance factor expressing the maximal volatility tolerance for a project or portfolio. For a low-risk portfolio its empirically found tolerance is apparently acceptable, and values exceeding this tolerance are used to trigger IT decision makers. We derived two volatility ratios from this model, the π-ratio and the ρ-ratio. These ratios express how close the volatility of a project has approached the danger zone when requirements volatility reaches a critical failure rate. The volatility data of a governmental IT portfolio were juxtaposed to our bancassurance benchmark, immediately exposing a problematic project, which was corroborated by its actual failure. When function points are less common, e.g. in the embedded industry, we used daily source code size measures and illustrated how to govern the volatility of a software product line of a hardware manufacturer. With the three real-world portfolios we illustrated that our results serve the purpose of an early warning system for projects that are bound to fail due to excessive volatility. Moreover, we developed essential requirements volatility metrics that belong on an IT governance dashboard and presented such a volatility dashboard.