全文获取类型
收费全文 | 9600篇 |
免费 | 588篇 |
国内免费 | 427篇 |
学科分类
工业技术 | 10615篇 |
出版年
2024年 | 30篇 |
2023年 | 185篇 |
2022年 | 288篇 |
2021年 | 380篇 |
2020年 | 324篇 |
2019年 | 301篇 |
2018年 | 233篇 |
2017年 | 430篇 |
2016年 | 387篇 |
2015年 | 339篇 |
2014年 | 468篇 |
2013年 | 712篇 |
2012年 | 833篇 |
2011年 | 822篇 |
2010年 | 521篇 |
2009年 | 478篇 |
2008年 | 406篇 |
2007年 | 517篇 |
2006年 | 402篇 |
2005年 | 362篇 |
2004年 | 359篇 |
2003年 | 263篇 |
2002年 | 247篇 |
2001年 | 202篇 |
2000年 | 194篇 |
1999年 | 176篇 |
1998年 | 119篇 |
1997年 | 90篇 |
1996年 | 73篇 |
1995年 | 89篇 |
1994年 | 66篇 |
1993年 | 54篇 |
1992年 | 57篇 |
1991年 | 43篇 |
1990年 | 34篇 |
1989年 | 17篇 |
1988年 | 19篇 |
1987年 | 19篇 |
1986年 | 19篇 |
1985年 | 11篇 |
1984年 | 12篇 |
1983年 | 11篇 |
1982年 | 7篇 |
1981年 | 5篇 |
1980年 | 6篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1975年 | 1篇 |
1951年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
1.
2.
JFC磷酸酯的合成和应用 总被引:2,自引:0,他引:2
详述了JFC磷酸酯的合成工艺路线,以及它在织物前处理精练工艺中的应用。与其它磷酸酯类精练剂性能对比,证明它可作为一种性能优良的精练剂中的添加剂。 相似文献
3.
简述国内磷酸二铵的建设情况及不同的生产工艺、原有磷酸二铵装置改造选用的工艺及生产情况 ,重点介绍 Incro工艺在云南红河州磷肥厂年产 12万吨磷铵装置中的改造情况 ,经过比较认为原采用预中和槽流程磷酸二铵装置增产改造时选用 Incro工艺比较合适 相似文献
4.
1Introduction Reconstructivesurgeryisoneofthehottestre searchedsubjectsthatdealingwithbonedefects.Thetra ditionalmethodisimplantationoffreshautograftbonebe causeofitsnon immunoreactiveproperty.Butautologousbonewasnotabundantinsomecases.Sowefoundbeta trica… 相似文献
5.
Lei Liu Ying Kong Hong Xu Jin P. Li Jin X. Dong Zhi Lin 《Microporous and mesoporous materials》2008,115(3):624-628
A three-dimensional zinc phosphate compound with DFT topology, designated as ZnPO4-EU1, has been synthesized by an ionothermal approach from the system HF-ZnO–P2O5-choline chloride-imidazolidone. Ethylenediamine, derived from decomposition of the imidazolidone component of the deep-eutectic solvent (DES) itself, is delivered to the synthesis and serves as an appropriate template for ZnPO4-EU1. Experiments in which the synthesis conditions were varied showed that ZnPO4-EU1 may be prepared over a wide molar ratio of P/Zn = 0.55–13.0. Powder X-ray diffraction patterns have been obtained at intervals to track the crystallization process of this material. The experimental data show that Zn3(PO4)2 · 4H2O (a dense phase) was first isolated from the DES after reaction for 1 h. Subsequently, the pure phase of ZnPO4-EU1 was obtained with increasing crystallization time from 12 h to 72 h. The experimental results show that the nucleation and crystallization take place with relatively low levels of solvent degradation, demonstrating that zinc phosphate with a three-dimensional framework can be synthesized by in situ generation of an appropriate template using an unstable DES at high temperatures (150–200 °C). 相似文献
6.
G. H. Palmir 《Journal of the Institute of Brewing》1987,93(4):332-333
The aleurone cells of barley, wheat, rice, rye, oats and triticale contained, comparatively, higher percentages of phosphorus than the aleurone cells of sorghum, maize or millet. The aleurone tissues of barley, wheat and rice had more phosphate than corresponding tissues of sorghum and maize. Phosphate was not detected in the aleurone tissue of maize but was found in trace amounts in the aleurone tissue of sorghum. 相似文献
7.
There is a need for developing low cost, easily and abundantly available, yet efficient, adsorbents for the removal of phosphates during the tertiary treatment of wastewaters. The tamarind nut shell activated carbon (TNSAC) prepared on a laboratory scale has been used to evaluate its performance for phosphate adsorption. This paper describes the laboratory production of this adsorbent material in its various forms, and discusses the effects of the TNSAC process variables (the unrinsed and rinsed forms of the TNSAC and the impregnation ratio) on its performance in adsorbing phosphate. The material has been shown to be a good alternative adsorbent. As much as 95% phosphate removal by the unrinsed TNSAC is possible in about 30 min under the test conditions. The phosphate adsorbing capacity is about two times higher for the unrinsed TNSAC in comparison to the rinsed TNSAC. The adsorption rates, however, transit to extremely low rates towards the end when equilibrium conditions could be attained in about 2 h contact time. The phosphate removal mechanics are adsorption and precipitation/ion exchange when unrinsed TNSAC is used, and adsorption alone for the rinsed TNSAC. The maximum phosphate removal is found to take place at an impregnation ratio of 1.0 for both forms of the TNSAC. 相似文献
8.
Yu. V. Balaban-Irmenin N. G. Fokina 《Power Technology and Engineering (formerly Hydrotechnical Construction)》2007,41(4):228-232
The reliability of heat-supply systems is determined primarily by internal corrosion of the pipelines. The concentration of
oxygen in the water exerts a major influence on the corrosion. In systems with a standard oxygen content, OéDF-Zn is a highly
effective corrosion inhibitor. However, there are systems in which the quality of deaeration of the make-up water of the heat-supply
system is low (or deaeration is nonexistent), and the concentration of oxygen is considerably above the standard value. Classed
among these systems, for example, are the HWS systems, which are incorporated into closed heat-supply systems. The oxygen
concentration in these systems is analyzed to assess the situation.
__________
Translated from élektricheskie Stantsii, No. 6, June 2007, pp. 35–39. 相似文献
9.
Expanded polytetrafluoroethylene (ePTFE) membranes were modified by graft copolymerization with methacryloxyethyl phosphate (MOEP) in methanol and 2‐butanone (methyl ethyl ketone (MEK)) at ambient temperature using gamma irradiation. The effect of dose rate (0.46 and 4.6 kGy h?1), monomer concentration (1–40 %) and solvent were studied and the modified membranes were characterized by weight increase, X‐ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). XPS was used to determine the % degree of surface coverage using the C? F (ePTFE membrane) and the C? C (MOEP graft copolymer) peaks. Grafting yield, as well as surface coverage, were found to increase with increasing monomer concentration and were significantly higher for samples grafted in MEK than in methanol solution. SEM images showed distinctly different surface morphologies for the membranes grafted in methanol (smooth) and MEK (globular), hence indicating phase separation of the homopolymer in MEK. We propose that in our system, the non‐solvent properties of MEK for the homopolymer play a more important role than solvent chain transfer reactions in determining grafting outcomes. Copyright © 2005 Society of Chemical Industry 相似文献
10.
磷酸酯淀粉在纯棉细特高密织物浆纱中的应用 总被引:2,自引:0,他引:2
就磷酸酯淀粉在纯棉细号高密织物中的上浆情况进行了试验,提出了具体浆纱工艺和减少织造断头率,提高织物效率及布面质量对策,实验表明,磷酸酯淀粉完全适应于纯绵细特高密织物的上浆要求。 相似文献