全文获取类型
收费全文 | 6020篇 |
免费 | 338篇 |
国内免费 | 320篇 |
学科分类
工业技术 | 6678篇 |
出版年
2024年 | 10篇 |
2023年 | 76篇 |
2022年 | 71篇 |
2021年 | 98篇 |
2020年 | 95篇 |
2019年 | 91篇 |
2018年 | 103篇 |
2017年 | 137篇 |
2016年 | 129篇 |
2015年 | 128篇 |
2014年 | 148篇 |
2013年 | 236篇 |
2012年 | 273篇 |
2011年 | 309篇 |
2010年 | 255篇 |
2009年 | 287篇 |
2008年 | 306篇 |
2007年 | 513篇 |
2006年 | 510篇 |
2005年 | 547篇 |
2004年 | 464篇 |
2003年 | 395篇 |
2002年 | 315篇 |
2001年 | 269篇 |
2000年 | 220篇 |
1999年 | 131篇 |
1998年 | 81篇 |
1997年 | 71篇 |
1996年 | 84篇 |
1995年 | 53篇 |
1994年 | 52篇 |
1993年 | 21篇 |
1992年 | 42篇 |
1991年 | 32篇 |
1990年 | 51篇 |
1989年 | 54篇 |
1988年 | 6篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 1篇 |
1984年 | 5篇 |
1983年 | 1篇 |
1981年 | 2篇 |
1979年 | 1篇 |
排序方式: 共有6678条查询结果,搜索用时 46 毫秒
1.
2.
3.
Calculations and detailed first principle and thermodynamic analyses have been performed to understand the formation mechanism of K2Ti6O13 nanowires (NWs) by a hydrothermal reaction between bulk Na2Ti3O7 crystals and a KOH solution. It is found that direct ion exchange between K+ and Na+ plus H+ interactions with [TiO6] octahedra in Na2Ti3O7 promote the formation of an intermediate H2K2Ti6O14 phase. The large lattice mismatch between this intermediate phase and the bulk Na2Ti3O7 structure, and the large energy reduction associated with the formation of this intermediate phase, drive the splitting of the bulk crystal into H2K2Ti6O14 NWs. However, these NWs are not stable because of large [TiO6] octahedra distortion and are subject to a dehydration process, which results in uniform K2Ti6O13 NWs with narrowly distributed diameters of around 10 nm. 相似文献
4.
以工业偏钛酸、硫酸锌、氨水为主要原料,用直接沉淀法并进行热处理得到钛酸锌粉体,并用XRD对产物成分进行了检测。结果表明,不同的锌钛比对钛酸锌(ZnO-TiO2)体系的成分有较大影响。 相似文献
5.
K Umakantham K Chandramouli G Nageswara Rao A Bhanumathi 《Bulletin of Materials Science》1996,19(2):345-355
Rare-earth doped strontium barium niobates were synthesized using usual ceramic technique. The dopants are La, Ce, Gd, Sm
and Nd. The materials were characterized by XRD and density measurements. The grain sizes were determined from SEM analysis.
Lattice parameters changed uniformly with rare-earth dopants in unfilled structures. Density measurements and SEM analysis
confirmed only minute changes in the densities of the ceramics. 相似文献
6.
用溶胶-凝胶法制备TiO2及TiO2/SiO2复合纳米材料,作为PBT(聚对苯二甲酸丁二酯)合成的催化剂,与现在普通使用的催化剂钛酸丁酯进行了比较和研究。结果发现,TiO2/SiO2复合纳米材料催化性能最好,纳米TiO2次之。 相似文献
7.
Study on Adsorption Behavior of Rare Earth Complexes on Nanometer-Size Titanium Dioxide with ICP-AES
Inrecentyears ,rareearthelements (REEs)havebeenwidelyusedinfunctionalmaterials ,cata lystsandotherproductsinindustry ,diagnosisreagentsofmagneticresonanceimaging (MRI)inmedicineandsomefertilizersinagricultureespeciallyinChina .However,asaresultoftheirusage ,moreandmoreREEsaregettingintotheenvironment,andalsointohumanbodyviafoodchain[1,2 ] .Itisnotclearwhetherrareearthelementsareessentialforman ,soitisveryurgenttostudythebiologicaleffectofrareearthelementsinhumanhealthandenvironment .Inthes… 相似文献
8.
本文概述了纳米科技的沿革,及其在国内外发展的情况,并就我国如何进一步发展纳米科技提出了自己的想法。 相似文献
9.
Humin Cheng Jiming Ma Zhenguo Zhao Di Qiang Yongxiang Li Xi Yao 《Journal of the American Ceramic Society》1992,75(5):1123-1128
A pure, acicular lead titanate (PbTiO3 ) fine powder with a white color has been prepared by hydrothermal synthesis. It is a new phase of PbTiO3 with I 4 symmetry, cell parameters of a = 12.358 Å and b = 14.541 Å, and a density of 6.80 g.cm−3 . The influences of pH (12.5 to 14.4), Pb/Ti ratio (1.0 to 1.6) in the feedstock, reaction temperature (130° to 230°C), time (0.25 to 4 h), starting materials, and additives on the formation of acicular PbTiO3 under hydrothermal conditions have been investigated. The acicular PbTiO3 with I 4 symmetry, referred to as the PX phase, can be converted to the perovskite-type (PE phase) of PbTiO3 at about 605°C while its acicular morphology is essentially unchanged. The preferable conditions for preparing pure acicular PX-phase PbTiO3 are that the pH is 13.0 to 14.0, Pb/Ti ratio is >1.3, reaction temperature is 170° to 200°C, time is 0.5 to 1.0 h, titanium butoxide (Ti[O(CH2 )3 CH3 ]4 ) is the starting material, and poly(vinyl alcohol) is an additive. The acicular grain of the PX phase is usually less than 100 nm in diameter and more than 1000 nm in length. 相似文献
10.
铸型尼龙改性的研究进展 总被引:4,自引:0,他引:4
铸型尼龙产品广泛地用于各种机械零件,改性后的铸型尼龙,可克服其自身的缺点,满足工业应用的要求。文章就我国近年来在铸型尼龙改性研究方面的情况及不同的改性方法做了详细的介绍。 相似文献