全文获取类型
收费全文 | 183篇 |
免费 | 58篇 |
国内免费 | 5篇 |
学科分类
工业技术 | 246篇 |
出版年
2024年 | 3篇 |
2023年 | 27篇 |
2022年 | 14篇 |
2021年 | 22篇 |
2020年 | 34篇 |
2019年 | 29篇 |
2018年 | 12篇 |
2017年 | 22篇 |
2016年 | 18篇 |
2015年 | 12篇 |
2014年 | 11篇 |
2013年 | 7篇 |
2012年 | 10篇 |
2011年 | 6篇 |
2010年 | 4篇 |
2009年 | 1篇 |
2008年 | 2篇 |
2007年 | 1篇 |
2006年 | 1篇 |
2005年 | 1篇 |
2004年 | 1篇 |
2003年 | 1篇 |
2001年 | 1篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1997年 | 2篇 |
1978年 | 1篇 |
1951年 | 1篇 |
排序方式: 共有246条查询结果,搜索用时 0 毫秒
1.
Janus粒子是同一粒子中含有两种不同化学组成的非对称结构,其中两亲性Janus粒子是在对立面分别含有亲水基、疏水基两种不同化学基团,作为一种新型纳米材料受到广泛的关注。该文综述了模板法制备不对称结构的两亲性Janus粒子以及其应用领域,包括硬模板法、软模板法、牺牲模板法以及无模板法;综述了两亲性Janus粒子在表面活性剂、牙科粘合剂、微胶囊、功能涂层、催化剂以及生物传感器等方面的研究进展。 相似文献
2.
3.
4.
Janus颗粒利用自身非对称的表面性质建立浓度梯度场,并在其作用下产生自驱动,在微机电系统、生物学、流体力学等领域具有重要的应用.本文首先建立了模拟这一过程的数值模型,并由Pt-SiO2型Janus微球的实验数据确定了迁移速率匹配常数.随后,研究了3种相同体积、不同形状的Janus颗粒的自驱动,结果表明,与相同体积的球形Janus颗粒相比,圆柱及椭球状Janus颗粒具有更快的自驱动速度,同时燃料消耗更多.对于圆柱状颗粒,研究了粗细程度对圆柱状颗粒自驱动性能的影响,结果表明存在最优的直径与长度比(d/l=0.28).这一研究可为Janus颗粒具体应用提供理论基础. 相似文献
5.
Multifunctional Silver‐Exchanged Zeolite Micromotors for Catalytic Detoxification of Chemical and Biological Threats 下载免费PDF全文
Virendra V. Singh Beatriz Jurado‐Sánchez Sirilak Sattayasamitsathit Jahir Orozco Jinxing Li Michael Galarnyk Yuri Fedorak Joseph Wang 《Advanced functional materials》2015,25(14):2147-2155
Multifunctional reactive‐zeolite‐based micromotors have been developed and characterized toward effective and rapid elimination of chemical and biological threats. The incorporation of silver ions (Ag+) into aluminosilicate zeolite framework imparts several attractive functions, including strong binding to chemical warfare agents (CWA) followed by effective degradation, and enhanced antibacterial activity. The new zeolite‐micromotors protocol thus combines the remarkable adsorption capacity of zeolites and the efficient catalytic properties of the reactive Ag+ ions with the autonomous movement of the zeolite micromotors for an accelerated detoxification of CWA. Furthermore, the high antibacterial activity of Ag+ along with the rapid micromotor movement enhances the contact between bacteria and reactive Ag+, leading to a powerful “on‐the‐fly” bacteria killing capacity. These attractive adsorptive/catalytic features of the self‐propelled zeolite micromotors eliminate secondary environmental contamination compared to adsorptive micromotors. The distinct cubic geometry of the zeolite micromotors leads to enhanced bubble generation and faster movement, in unique movement trajectories, which increases the fluid convection and highly efficient detoxification of CWA and killing of bacteria. The attractive capabilities of these zeolite micromotors will pave the way for their diverse applications in defense, environmental and biomedical applications in more economical and sustainable manner. 相似文献
6.
7.
Aspects of the self-assembly of particles, which uses nanometer or micrometer sized building blocks to bridge the gap between microscopic and macroscopic scales, are reviewed. Particle self-assembly has been the focus of considerable research in recent years because it can lead to superstructures with a complexity inaccessible by molecular self-assembly, and functionalities entirely different from or superior to those of the primary particles. Examples in molecular self-assembly suggests that anisotropic interactions could be useful in promoting particle self-assembly, with the exception of colloidal crystallization, which requires particles of uniform size and shape. Anisotropic particles prepared by surface modification of precursor particles are often rigid and submicron or micron sized, and thus relatively strong isotropic van der Waals interactions tend to resist self-assembly into regular superstructures. In addition, the relatively large contact area between particles needed for a sufficient binding enthalpy to stabilize a superstructure is difficult for rigid spherical particles. In contrast, flexible anisotropic polymeric particles dispersed in solvents have been shown to self-assemble into various superstructures. The flexibility of primary anisotropic particles enables them to fuse and stabilize into a superstructure. Some flexible and multi-component particles that are isotropic in common solvents can undergo deformation and sufficient material redistribution to anisotropically self-assemble into regular superstructures in selective solvents. The self-assembly is also driven by anisotropic interactions, which is induced during self-assembly rather than in the particles as synthesized. This review focuses on recent achievements in soft particle self-assembly and describes briefly the advancements in rigid particle self-assembly. The presentation is divided into discussion of self-assembly by the colloidal crystallization of isotropic rigid particles, anisotropic rigid particles, anisotropic soft particles and isotropic soft particles, in that order. 相似文献
8.
Precise Molecular Sieving Architectures with Janus Pathways for Both Polar and Nonpolar Molecules 下载免费PDF全文
Jiangtao Liu Dan Hua Yu Zhang Susilo Japip Tai‐Shung Chung 《Advanced materials (Deerfield Beach, Fla.)》2018,30(11)
Precise molecular sieving architectures with Janus superhighways are constructed via a molecularly engineered interfacial reaction between cyclodextrin (CD) and trimesoyl chloride (TMC). Interestingly, the CD/TMC nanofilms constructed with both hydrophobic inner cavities and hydrophilic channels exhibit exceptionally high permeances for both polar and nonpolar solvents. The precise molecular sieving functions are determined by the type of CD building blocks and the inner cavities of intrinsic 3D hollow bowls. Positron annihilation spectroscopy (PAS) confirms that a larger inner CD cavity tends to generate a larger free volume and higher microporosity. Based on the rejection ratio of various dyes, the estimated molecular weight cutoff of CD/TMC nanofilms follows the trend of α‐CD/TMC (320 Da) <β‐CD/TMC (400 Da) <γ‐CD/TMC (550 Da), which is in strict accordance with the orders of their free volumes measured by PAS and inner cavity sizes of α‐CD <β‐CD <γ‐CD. This kind of novel CD/TMC molecular sieving membrane with intrinsic microporosity containing tunable pore size and sharp pore‐size distribution can effectively discriminate molecules with different 3D sizes. 相似文献
9.
10.