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1.
2.
A set of poly[N‐oligo(ethylene oxide)yl 4‐vinylpyridinium tosylate] (P4VOEOOTs) has been prepared by spontaneous polymerization of 4‐vinylpyridine. This method gives a grafted polyelectrolyte having a positive charge on every backbone pyridinic moiety. The P4VP15Ts, P4VP164Ts, P4VP350Ts and P4VP750Ts aqueous solution conductivities were determined in the concentration range from 6 × 10?4 to 10?2 M at 25 °C. The variation of the conductivity versus concentration of the investigated system exhibits typical polyelectrolyte behaviour. The polyelectrolyte mobility was found to be dependent on the oligo(ethylene oxide) (OEO) side‐chain length. Manning's rod‐like model fails to describe these results. A simple steric effect is proposed to explain the influence of the OEO length. Copyright © 2003 Society of Chemical Industry 相似文献
3.
为了提高非稳定渗流计算的计算精度 ,通过数学分析得到了水位传导系数随时间变化时 ,一类非稳定渗流井流模型的半解析解 ,并进行了计算比较 相似文献
4.
磁处理技术是利用磁场对非铁磁性流体作用.使被作用物的性质产生某些期望的变化,从而改善生产效果和使用效益。磁处理对常规钻井液流变性能的影响研究结果表明,磁化能明显改善钻井液性能。通过研究磁化后泡沫钻井液的性质.测定与控制钻井液的电导率,以便从电测曲线上取得更好的地层特性评价。泡沫钻井液的电导率与密度基本呈线性关系,电导率随密度的升高而变大;磁处理后泡沫钻井液的性质发生明显改变.泡沫钻井液的电导率有不同程度的下降,在磁场强度为100mT、蜂数为2的磁场条件下泡沫钻井液的电导率变化率降低最大,电导率平均下降16%左右。 相似文献
5.
The d.c. electrical conductivity of sodium vanadate, rubidium vanadate, cesium vanadate and their solid solutions sodium-rubidium
vanadate and sodium-cesium vanadate were studied by a two-probe method in the temperature range covering their transition
points. The electrical conductivity shows sharp change at the phase transition temperature of these materials. In NaVO3, RbVO3 and CsVO3, increase in d.c. conductivity is observed in the ferroelectric region while nonlinearities are observed above transition
temperatures. In solid solutions, the activation energy in the paraelectric state is higher than that in the ferroelectric
state and depends upon sodium concentration. 相似文献
6.
7.
ZnS, ZnSe, and CdTe polycrystals are experimentally investigated. Mechanisms are treated which restrict the thermal conductivity in samples prepared by recrystallization pressing and by deposition from the vapor phase and subjected to additional strain. Anomalies are observed on the temperature dependences of the thermal resistance of investigated samples, which are due to the special features of their phonon spectra and to the variation of the contribution made by longitudinal and transverse phonon branches to the heat transfer in the Debye temperature region and higher. 相似文献
8.
E. M. Abdel-Bary H. H. Hassan A. M. El-Lawindy M. K. Abu-Assy F. K. El-Tantawy 《Polymer International》1993,30(3):371-374
Butyl rubber mixtures loaded with 70 phr general purpose furnace black (GPF) and tetramethyl thiuram disulphide (TMTD)/S as vulcanizing system were prepared. The kinetics of their electrical conductivity development during the vulcanization process were followed by using an especially devised system. It was found that the increase in the electrical conductivity during vulcanization obeys an exponential growth function with time constant τ, which markedly decreases with increasing vulcanization temperature as well as with the efficiency of the vulcanizing system. After completion of the vulcanization process, about 80 min, the samples obtained possess reasonable stability and reproducibility of electrical conductivity. 相似文献
9.
András Ványolos Balázs Dóra Attila Virosztek 《Journal of Superconductivity and Novel Magnetism》2007,20(7-8):643-645
We report of a theoretical study on quasi-one dimensional unconventional charge density wave (UCDW) driven by electron–phonon
interaction. Within mean field theory, we find that the wavevector dependence of the coupling leads to a momentum dependent
single particle gap on the Fermi surface. The presence of small energy single particle excitations around the gap nodes significantly
changes the optical conductivity compared to the conventional CDW result. In addition to that, the collective phase excitation
arising from fluctuation of the order parameter leads to further qualitative changes of the conductivity and results in an
effective mass that is nonmonotonic in temperature.
相似文献
10.
The compositions (1 −x)Ag2SO4−(x)BaSO4, wherex=0·01 to 0·6, were prepared by slow cooling of the melt. The extent of the solid solubility of Ba2+ in Ag2SO4 was determined by X-ray powder diffraction and scanning electron microscopy. The bulk conductivity of each sample was obtained
using a detailed impedance analysis. The partial substitution of Ba2+ results in the enhancement of conductivity in compliance with the classical aliovalent doping theory. A simplistic model
based on lattice distortion (expansion) due to partial substitution of Ag+ by the bigger Ba2+ has been considered to explain enhanced conductivity. Beyond solid-solubility limit (5·27 mole%) the BaSO4-dispersed Ag2SO4 conductivity follows the usual trend seen in binary systems. An increase in conductivity in this case is discussed in the
light of interfacial reactions and surface defect chemistry. The maximum conductivity in 20 mole% BaSO4 dispersed Ag2SO4 is due to percolation threshold. 相似文献