全文获取类型
收费全文 | 1186篇 |
免费 | 178篇 |
国内免费 | 69篇 |
学科分类
工业技术 | 1433篇 |
出版年
2024年 | 7篇 |
2023年 | 40篇 |
2022年 | 31篇 |
2021年 | 65篇 |
2020年 | 56篇 |
2019年 | 51篇 |
2018年 | 46篇 |
2017年 | 40篇 |
2016年 | 51篇 |
2015年 | 45篇 |
2014年 | 60篇 |
2013年 | 73篇 |
2012年 | 69篇 |
2011年 | 69篇 |
2010年 | 56篇 |
2009年 | 86篇 |
2008年 | 52篇 |
2007年 | 68篇 |
2006年 | 71篇 |
2005年 | 46篇 |
2004年 | 51篇 |
2003年 | 46篇 |
2002年 | 44篇 |
2001年 | 35篇 |
2000年 | 40篇 |
1999年 | 20篇 |
1998年 | 13篇 |
1997年 | 11篇 |
1996年 | 8篇 |
1995年 | 9篇 |
1994年 | 10篇 |
1993年 | 7篇 |
1992年 | 16篇 |
1991年 | 11篇 |
1990年 | 12篇 |
1989年 | 9篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1982年 | 2篇 |
1979年 | 2篇 |
排序方式: 共有1433条查询结果,搜索用时 15 毫秒
1.
Ram Bilas 《Bulletin of Materials Science》1993,16(2):109-116
X-ray diffraction, electron paramagnetic resonance, microwave absorption and resistivity measurements were carried out on
YBa2−x
Bi
x
Cu3O7 (0≤x≤0·5) superconductors in order to study the effect of bismuth on the structural and superconducting properties. A decrease
in sintering temperature increased the amount of impurity phase. Transition from an orthorhombic (superconducting) phase to
tetragonal structure produced no significant change in EPR zero-field signal at liquid nitrogen temperature (LNT). The non-resonance
signal height decreased on higher concentration of bismuth. Sintered YBa2−x
Bi
x
Cu3O7 superconductor had a strong EPR zero-field signal at LNT. We have evaluated particle size from XRD and EPR studies. The average
particle size was about 0·4μm. 相似文献
2.
叙述了从铅阳极泥回收金银后的渣料中综合回收有价金属的生产实践。根据渣料性质,将火法和湿法工艺相互结合,使渣料中的锑、铋、金、银、铅、铜得以较彻底的分离和回收。 相似文献
3.
Control over crystallographic orientation in ceramic thin films is important for highly anisotropic structures. Layered perovskites, like Bi4 Ti3 O12 , have interesting properties associated with their ferroelectric nature, which may be fully exploited only when films are highly textured. Textured films of this titanate were fabricated via a sol–gel technique without using epitaxial growth. Orientation in the film is confirmed by XRD and SEM, and supported by refractive index and dielectric measurements. In an attempt to explain the orienting effect, light scattering experiments were conducted to yield information about the molecular size, shape, and conformation of macromolecules as the sol–gel solution ages and condensation reactions proceed. These experiments clearly show an increase in the size of molecular clusters with time. We believe that it is the organization of these large clusters during spin coating, and the relationship of the backbone chemistry to the crystal structure of Bi4 Ti3 O12 , that are responsible for the observed orientation. 相似文献
4.
从铅阳极泥中回收铋的火法工艺实践 总被引:4,自引:2,他引:2
主要论述了从铅阳极泥中回收铋的全火法工艺流程改造与实践,并取得了预期的效果。 相似文献
5.
(反应)模晶生长法制备NBT-6BT织构陶瓷的研究 总被引:1,自引:0,他引:1
以熔盐法合成的片状SrTiO3,Bi4Ti3O12为种晶,分别采用模晶生长法(TGG)和反应模晶生长发(RTGG)制备了具有〈001〉取向的0.94(Na1/2Bi1/2)TiO3-0.06BaTiO3(NBT-6BT)织构陶瓷。研究了不同种晶选择、流延和热处理工艺参数对陶瓷织构化程度、显微结构和压电性能的影响。结果表明,RTGG制备的织构陶瓷比TGG的在结构和性能等方面都具有优势,且用该方法以Bi4Ti3O12为种晶,制备出了高密度(f≥96%)、高织构度(F≈95%)、高性能(d33≈241pC/N)的NBT-6BT无铅压电陶瓷。 相似文献
6.
Toshio Kimura Toru Takahashi Toshihiko Tani Yasuyoshi Saito 《Journal of the American Ceramic Society》2004,87(8):1424-1429
Bi0.5 Na0.5 TiO3 (BNT) and 0.94Bi0.5 Na0.5 TiO3 ·0.06BaTiO3 (BNT–BT) bulk ceramics with extensive 〈100〉 texture were prepared by the reactive-templated grain growth method, using platelike Bi4 Ti3 O12 (BIT) particles as templates for BNT. Calcined compacts were composed of matrix grains with random orientation and 〈100〉-oriented grains transformed from aligned BIT particles, and the texture developed by the growth of oriented grains during sintering. Ceramics with extensive texture were obtained by using the starting mixture containing the maximum concentration of platelike BIT to form the maximum volume fraction of oriented grains. 相似文献
7.
8.
用DSC研究了高T_e超导体B_(2-r)Pb_rSr_2Ca_2Cu_sO_v(x=0,0.2,0.4,0.6)从室温至600℃范围内的相变。在320℃和440℃附近有二个吸热蜂,每一个峰对应一个相变过程。440℃附近的相变是不可递的,其原子激活能为1.37eV,是由高T_e相向低T_e相的转变。而320℃附近的相变则与超结构的形成有关。 相似文献
9.
Mohammad A. Alim 《Journal of the American Ceramic Society》1989,72(1):28-32
The lumped parameter/complex plane analysis technique revealed several contributions to the terminal admittance of the ZnO—Bi2 O3 based varistor grain-boundary ac response. The terminal capacitance has been elucidated via the multiple trapping phenomena, a barrier layer polarization, and a resonance effect in the frequency range 10−2 ≤ f ≤ 109 Hz. The characterization of the trapping relaxation behavior near ∼ 105 Hz (∼ 10−6 s) provided a better understanding of a previously reported loss-peak. The possible nonuniformity in this trapping activity associated with its conductance term observed via the depression angle of a semicircular relaxation in the complex capacitance ( C *) plane has been postulated. 相似文献
10.
以三聚氰胺为前驱体,采用简单的热聚合方法制备了超薄石墨相氮化碳(g-C3N4),并用原位沉积-沉淀法在g-C3N4表面生成碘氧化铋(BiOI),复合构筑不同BiOI质量占比的二维碘氧化铋/石墨相氮化碳(2D/BiOI/g-C3N4,BICN-x)Z型异质结用以协同过二硫酸盐(PS)。通过XRD、FTIR、SEM、HRTEM、BET、UV-vis DRS对光催化剂的结构、表面官能团、形貌特征、比表面积和光学性能进行表征分析。结果表明:BiOI与g-C3N4质量比为2∶1(BICN-3)时,通过密切的界面耦合,光生电子-空穴对分离效率较高,光生e-以更快的迁移速度到达结构表面,并且在LED照射60 min内,BICN-3与PS形成的催化体系(BICN-3/PS)去除了88.2%的四环素(TC,10mg/L),降解速率是单独BICN-3的3.82倍。 相似文献