全文获取类型
收费全文 | 32407篇 |
免费 | 3356篇 |
国内免费 | 2419篇 |
学科分类
工业技术 | 38182篇 |
出版年
2024年 | 144篇 |
2023年 | 1015篇 |
2022年 | 1216篇 |
2021年 | 1319篇 |
2020年 | 1331篇 |
2019年 | 1193篇 |
2018年 | 1085篇 |
2017年 | 1266篇 |
2016年 | 1104篇 |
2015年 | 1080篇 |
2014年 | 1496篇 |
2013年 | 1597篇 |
2012年 | 1896篇 |
2011年 | 2229篇 |
2010年 | 1451篇 |
2009年 | 1799篇 |
2008年 | 1465篇 |
2007年 | 1914篇 |
2006年 | 1809篇 |
2005年 | 1532篇 |
2004年 | 1378篇 |
2003年 | 1311篇 |
2002年 | 1127篇 |
2001年 | 1051篇 |
2000年 | 966篇 |
1999年 | 680篇 |
1998年 | 605篇 |
1997年 | 531篇 |
1996年 | 445篇 |
1995年 | 417篇 |
1994年 | 292篇 |
1993年 | 228篇 |
1992年 | 255篇 |
1991年 | 223篇 |
1990年 | 241篇 |
1989年 | 203篇 |
1988年 | 81篇 |
1987年 | 38篇 |
1986年 | 26篇 |
1985年 | 14篇 |
1984年 | 22篇 |
1983年 | 10篇 |
1982年 | 14篇 |
1981年 | 13篇 |
1980年 | 12篇 |
1979年 | 16篇 |
1978年 | 8篇 |
1976年 | 6篇 |
1975年 | 8篇 |
1951年 | 11篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
1.
Hao Li Pengcheng Zhang Shengquan Yu Hongyu Yang Bin Tang Fuhai Li Shuren Zhang 《Ceramics International》2019,45(9):11639-11647
Mg2(Ti1-xSnx)O4 (x?=?0–1) ceramics were prepared through conventional solid-state method. This paper focused on the dependence of microwave dielectric properties on crystal structural characteristics via crystal structure refinement, Raman spectra study and complex chemical bond theory. XRD spectrums delineated the phase information of a spinel structure, and structural characteristic of these compositions were achieved with the help of Rietveld refinements. Raman spectrums were used to depict the correlations between vibrational phonon modes and dielectric properties. The variation of permittivity is ascribed to the Mg2(Ti1-xSnx)O4 average bond covalency. The relationship among the B-site octahedral bond energy, tetrahedral bond energy and temperature coefficient are discussed by defining on the change rate of bond energy and the contribution rate of octahedral bond energy. The quality factor is affected by systematic total lattice energy, and the research of XPS patterns illustrated that oxygen vacancies can be effectively restrained in rich oxygen sintering process. Obviously, the microwave dielectric properties of Mg2(Ti1-xSnx)O4 compounds were obtained (= 12.18, ?=?170,130?GHz, ?=??53.1?ppm/°C, x?=?0.2). 相似文献
2.
《Journal of the European Ceramic Society》2020,40(8):3348-3353
Large transduction coefficient () is difficult to obtain in piezoelectric ceramics because these two parameters show opposite trends with compositional modifications. Herein, the Pb(Zr0.53Ti0.47)O3 ceramic powders were calcinated under different temperatures (A:830 °C, B:860 °C, and C:890 °C), and then mixed together according to different weight ratios (1A:1B:1C, 1A:2B:1C, 1A:2B:3C and 3A:2B:1C) for ceramics preparation. Both d33 and g33 are improved successfully, and the transduction coefficient with the weight ratio of 1A:2B:3C reaches up to 17,500 × 10−15 m2/N, which is 60 % higher than that with the powders calcinated under 830 °C, and at least twice those of commercial PZT-4, PZT-5A and PZT-8 ceramics. The improved transduction coefficient is owing to the enhanced piezoelectric constant and spontaneous polarization resulted from the increased grain size, relative density and the fraction of tetragonal phase. These results indicate that this is a simple but effective way to tailor the transduction coefficient in piezoelectric ceramics. 相似文献
3.
John Bensted 《Cement and Concrete Composites》2003,25(8):873-877
Two main formation routes for thaumasite exist below 15 °C. One is the direct route from C–S–H reacting with appropriate carbonate, sulfate, Ca2+ ions and excess water. The other route is the woodfordite route from ettringite reacting with C–S–H, carbonate, Ca2+ ions and excess water, in which thaumasite arises through the intermediate formation of the solid solution woodfordite. The woodfordite route for thaumasite formation appears to be relatively quicker (although still slow) than the direct route, presumably because with the former the ettringite already has the octahedral [M(OH)6] units that can facilitate the critical change from [Al(OH)6]3− to [Si(OH)6]2− groupings. Both routes are mutually dependent on each other. The presence of magnesium salts can modify the path to thaumasite formation. High pressure might be able to stabilise [Si(OH)6]2− groupings and allow thaumasite to become formed above 15 °C. This possibility is discussed. 相似文献
4.
5.
通过龙潭水电站对励磁装置可控硅元件实施过电压保护改进前后实际效果的分析,介绍了一种有效的过压保护方式. 相似文献
6.
7.
由于干态聚合物电解质目前还不能满足聚合物锂离子电池的应用要求,人们致力于开发含液体增塑剂的聚合物电解质,包括凝胶型和微孔型两类体系。本文综述了含液聚合物电解质的最新进展,重点论述了各种新体系和新方法。 相似文献
8.
J. Gegner 《Materialwissenschaft und Werkstofftechnik》2003,34(3):290-297
Chemical Composition and Microstructure of Polymer‐Derived Glasses and Ceramics in the Si–C–O System. Part 2: Characterization of microstructure formation by means of high‐resolution transmission electron microscopy and selected area diffraction Liquid or solid silicone resins represent the economically most interesting class of organic precursors for the pyrolytic production of glass and ceramics materials on silicon basis. As dense, dimensionally stable components can be cost‐effectively achieved by admixing reactive filler powders, chemical composition and microstructure development of the polymer‐derived residues must be exactly known during thermal decomposition. Thus, in the present work, glasses and ceramics produced by pyrolysis of the model precursor polymethylsiloxane at temperatures from 525 to 1550 °C are investigated. In part 1, by means of analytical electron microscopy, the bonding state of silicon was determined on a nanometre scale and the phase separation of the metastable Si–C–O matrix into SiO2, C and SiC was proved. The in‐situ crystallization could be considerably accelerated by adding fine‐grained powder of inert fillers, such as Al2O3 or SiC, which permits effective process control. In part 2, the microstructure is characterized by high‐resolution transmission electron microscopy and selected area diffraction. Turbostratic carbon and cubic β‐SiC precipitate as crystallization products. Theses phases are embedded in an amorphous matrix. Inert fillers reduce the crystallization temperature by several hundred °C. In this case, the polymer‐derived Si–C–O material acts as a binding agent between the powder particles. Reaction layer formation does not occur. On the investigated pyrolysis conditions, no crystallization of SiO2 was observed. 相似文献
9.
10.