MPID─TOF质谱的快速时间分辨微弱信号测试系统

把瞬态记录仪Ｂｉｏｍａｔｉｏｎ８ｌ００与微型计算机ＩＢＭ─ｐＣ／ＸＴ联接建成了一个高速数据采集系统，本文介绍了系统的硬件接口设计及软件设计。在超声分子束条件下，把它应用于环氧乙烷（Ｃ＿２Ｈ＿４Ｏ）的多光子电离与离解飞行时间（ＭＰＩＤ─ＴＯＦ）质谱的实验研究中，并给出了实验结果；本系统在微观基元化学反应动力学实验研究中广泛适用于对时间分辨微弱信号的探测。     

Stabilization of bioethanol recovery with silicone rubber‐coated ethanol‐permselective silicalite membranes by controlling the pH of acidic feed solution

In order to produce highly concentrated bioethanol by pervaporation using an ethanol‐permselective silicalite membrane, techniques to suppress adsorption of succinic acid, which is a chief by‐product of ethanol fermentation and causes the deterioration in pervaporation performance, onto the silicalite crystals was investigated. The amount adsorbed increased as the pH of the aqueous succinic acid solution decreased. The pervaporation performance also decreased with decreasing pH when the ternary mixtures of ethanol/water/succinic acid were separated. Using silicalite membranes individually coated with two types of silicone rubber, pervaporation performance was significantly improved in the pH range of 5 to 7, when compared with that of non‐coated silicalite membranes in ternary mixtures of ethanol/water/succinic acid. Moreover, when using a silicalite membrane double‐coated with the two types of silicone rubber, pervaporation performance was stabilized at lower pH values. In the separation of bioethanol by pervaporation using the double‐coated silicalite membrane, removal of accumulated substances having an ultraviolet absorption maximum at approximately 260 nm from the fermentation broth proved to be vital for efficient pervaporation. Copyright © 2005 Society of Chemical Industry     

Distinctiveness and Correlation in Conceptual Structure: Behavioral and Computational Studies.

Patients with category-specific deficits have motivated a range of hypotheses about the structure of the conceptual system. One class of models claims that apparent category dissociations emerge from the internal structure of concepts rather than fractionation of the system into separate substores. This account claims that distinctive properties of concepts in the living domain are vulnerable because of their weak correlation with other features. Given the assumption that mutual activation among correlated properties produces faster activation in the normal system, the authors predicted a disadvantage for the distinctive features of living things for unimpaired adults. Results of a speeded feature verification study supported this prediction, as did a computational simulation in which networks mapped from orthography to semantics. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

A Genetic Dissociation of Learning and Recall in Caenorhabditis elegans.

A learning event can be dissociated into 3 components: acquisition, storage, and recall. When the laboratory wild-type strain of Caenorhabditis elegans (N2 strain) is exposed to benzaldehyde in the absence of food, the worms display a reduction of their attractive response to this volatile odorant. This results from the association between benzaldehyde and a nutrient-deficient environment. Another wild-type isolate, the CB4856 strain, fails to display this decreased response to benzaldehyde after exposure to benzaldehyde in the absence of food. However, like the N2 strain, when tested to isoamyl alcohol after benzaldehyde conditioning, the CB4856 strain displays a decreased isoamyl alcohol response. Therefore, the CB4856 strain does not have an acquisition deficit, but it suffers from a recall deficit specific to benzaldehyde. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

New strategies for separations through reactions

Separations through reactions can provide reliable and economically viable alternatives to established methods of separation, particularly for close boiling substances. New strategies in ‘Dissociation Extraction’ and ‘Dissociation Extractive Crystallization’ for separation of close boiling acidic/basic mixtures have been highlighted. Separations with aqueous solutions of hydrotrope and aqueous micellar solutions have been brought out. Separations by membranes with facilitated transport is potentially attractive. This paper is dedicated to Dr L K Doraiswamy on his sixtieth birthday.     

电导法测定乙酸解离常数实验数据处理软件设计

介绍了用电导法测定乙酸解离常数的实验原理和步骤,给出了用计算机对电导法测定乙酸解离常数的实验数据进行处理的软件设计方法,同时给出了用Visual FoxPro 6.0编写电导法测定乙酸解离常数的处理软件的基本结构和部分程序代码。     

离子交换膜间水的电离及其应用

本文通过分析纯水的电离,讨论了普通电渗析(ED)和填充床电渗析(EDI)中水的电离现象及其相关 机理。EDI过程中水电离产生的H+和OH-离子可以自再生离子交换树脂。文中简单介绍了已得到产业化的EDI 技术和正在推广中的离子交换树脂的电再生技术。     

Ammonia synthesis: The bellwether reaction in heterogeneous catalysis

This is a personal account of the Havreholm Conference with a choice of topics dealing with catalytic ammonia synthesis. Among the general concepts that were retained are: the rate determining step with rates of adsorption and desorption of nitrogen; the direct activated dissociative adsorption of N₂; the surface crystalline anisotropy of iron; the role of promoters in industrial iron based catalysts; and the atomic structure of the metallic surface on the industrial multiply promoted catalyst. Finally, a new isotope jump technique to measure an upper limit to the real turnover frequency is discussed.     

Unsteady radiative heat transfer within a suspension of ZnO particles undergoing thermal dissociation

An emitting, absorbing, and anisotropically scattering plain medium containing a suspension of ZnO particles is considered, in which the particles are directly exposed to high-flux irradiation and undergo shrinkage during their endothermic dissociation into Zn(g) and O₂ at above 2100 K. The unsteady energy equation that links the rate of radiative heat transfer to the rate of the chemical reaction is formulated and solved numerically by the finite volume technique and the explicit Euler time-integration scheme. The path-length Monte Carlo method is applied for modeling the radiative transfer within the suspension using the absorption/scattering coefficients and the scattering phase function obtained from the Mie theory. It is found that the particle suspension can be heated rapidly from its initial 300 K to over 1800 K in less than 0.1 s, resulting in a more uniform temperature profile as the reaction progresses, particles shrink, and the suspension becomes optically thinner. The chemical conversion increases with decreasing initial particle diameter and volume fraction due to the efficient radiative absorption.     

连续逆流解离萃取法分离间氯苯胺及对氯苯胺

以萃取酸为连续相，应用填料塔设备对间氯苯胺及对氯苯胺混合物进行连续解离萃取以提纯间氯苯胺。实验考察了不同填料、塔高、停留时间等因素对分离效果的影响，并根据实验数据及成品纯度要求设计了塔的级数，完成了分离试验，分离后间氯苯胺纯度大于99％。