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1.
Jatuporn Wittayakun Pongtanawat Khemthong Sanchai Prayoonpokarach 《Korean Journal of Chemical Engineering》2008,25(4):861-864
Rice husk silica (RHS) in amorphous phase with 98% purity was prepared from a waste rice husk from rice milling by leaching
with hydrochloric acid and calcination. The RHS was used effectively as a silica source for the synthesis of zeolite Y in
sodium form (NaY). The zeolite in pure phase was obtained from a two-step synthetic route in which the starting gels were
mixed, aged for 24 h at room temperature and crystallized for 24 h at 90 °C. The diameter of single crystal particles from
a scanning electron microscope was approximately 1.0 μm, whereas the average particle diameter from laser diffraction particle
size analyzer was approximately 10 μm because of the agglomeration of small crystals. Longer crystallization time in this
route resulted in a mixed phase containing NaY and zeolite P in sodium form (NaP). In addition, a one-step synthetic route
(no aging) was studied and the product was also a mixed phase zeolite. 相似文献
2.
Beatriz O. Hincapie Luis J. Garces Sinue Gomez Ruma Ghosh Steven L. Suib 《Catalysis Today》2005,110(3-4):323
Copper containing faujasite has been successfully prepared for the first time using a direct synthesis method. Faujasite type zeolite can be prepared in the presence of copper species by tuning the synthesis conditions. Ammonium hydroxide was used to form a copper complex that was later mixed with the reacting gel. Sodium is required to obtain copper faujasite. The complete elimination of sodium ions from the starting gel produces amorphous material. Crystallization took place at 358 K for 11 days. Crystallization temperature of 373 K produces ANA type zeolite as an impurity. Increasing by two times the amount of copper complex added to the reacting gel increases the crystallization time of Cu-FAU from 11 to 20 days (the crystallization rate decreases). The copper containing faujasite obtained was characterized by XRD, FESEM, EDX, EPR, FT-IR, TPR, and BET. According to the XRD pattern only FAU type zeolite was obtained. According to TPR experiments, the reduction temperature for Cu2+ ions present in Cu-FAU prepared by direct synthesis was 70 K more than for Cu-FAU prepared by ion-exchange. This difference can be due to the different location of the copper ions in the supercages or in the sodalite cages of the faujasite. 相似文献
3.
The Y2O3: Yb3 , Er3 microstructures were fabricated by a hydrothermal method without surfactants.The microstructures structure was characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM,KYKY 1000B).The up-conversion luminescence spectra were studied under 978 nm laser diode excitation.In Yb3 and Er3 codoped Y2 O3 microcrystals, the relative intensity of green emission became stronger as the morphology of sample changed from wires to films. 相似文献
4.
天桥水电站是黄河中游北干上的第一座高泥沙、低水头、大流量的径流式试验电站。它成功的施工与运营经验不仅对在黄河中游北干上开发梯级水电站,而且对中小型径流式水电站的施工都具有重要的借鉴作用。这篇文章总结了两期截流工程、基坑排水、固结灌浆、帷幕灌浆方面的施工经验。在诸如厂房位置的选择以及它的布置,泥沙、冰凌、洪水以及拦污方面的工程设计与运营的宝贵经验,使得水库长期保持高的有效库容和良好的运营状态。特剐是防止进水口淤积和水轮机的磨蚀方面的七条措施是非常有价值的。 相似文献
5.
6.
Y1.94-xMgxO2S:0.06Ti (0≤x≤0.10) phosphors with long afterglow were synthesized by solid state reaction route. The photoluminescence spectra, decay curves, thermoluminescent spectra and chromaticity coordinate curves were investigated. The results show that the luminescence intensity of Y1.94-xMgxO2S:0.06Ti (0≤x≤0.10) phosphors decrease gradually with increasing Mg2 ion content, and the shape of luminescence spectra and chromaticity coordinate change as well. Furthermore, two thermoluminescent peaks in single Ti-doped Y2O2S sample are found at 91.8 and 221.5 ℃, respectively. Nevertheless, significant different spectra were found for the Mg, Ti co-doped Y2O2S samples that three thermoluminescence peaks appear at 52.3, 141.7 and 226.8 ℃, respectively. These results indicate that the co-doped Mg ion changes the inherent trap depth of single Ti-doped Y2O2S:Ti phosphor, and induces simultaneously a new trap level in the Y1.94-xMgxO2S:0.06Ti phosphor. Based on the analysis of thermoluminescent spectra, photoluminescent spectra, decay curve and crystal structure defect, it was proposed that the varied structure defect and introduced new trap level by the doped Mg2 ions should be responsible for reducing luminescence intensity and varying color in the Y1.94-xMgxO2S:0.06Ti phosphor. 相似文献
7.
分析了我厂两碱法原卤净化后,加热管内壁结碳酸钙垢的原因,探讨了我厂采取加盐酸、加阻垢剂、用超声波阻垢器的方法,以及对加热管内碳酸钙垢防治的情况和存在的问题. 相似文献
8.
9.
The activation of propane using zeolite H-Y and Ga3+ exchanged zeolite Y indicates that in the presence of Ga3+ the mechanism of propane activation is changed from a cracking pathway to a dehydrogenation pathway. The presence of both Ga3+ and H+ are required to achieve this effect. 相似文献
10.
研究了在250℃、不同挤压比下挤压变形对Mg95 Zn4.3 Y0.7合金组织及性能的影响。结果表明,Mg95 Zn4.3 Y0.7经过挤压变形后,合金中晶界处的共晶相破碎,弥散分布至晶粒内部,并且晶粒显著细化。同时,随着挤压比的增大,晶粒细化程度增加,合金的力学性能单调增加。当挤压比为16时,合金晶粒尺寸为5-8μm,抗拉强度为288.9MPa,显微硬度HV值为117.8。 相似文献