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1.
以邻苯二胺为原料合成表征了一类喹喔啉衍生物;1-烷基-3-甲基-2(1H)-喹喔啉-2-酮(1-alkyl-3-methly-2(1H)-quinoxalin-2-one,简称AMQ,其中alky=H、CH3、Et、n-C3H5、n-C5H11、n-C16H33)。用电子轰击电离质谱(EI-MS)和核磁共振谱图(^1H-NMR)鉴定了AMQ,研究了不同取代基对这类化合物EI-MS谱图的影响,分析得到一些裂解规律。结果表明:所有样品谱图中均有芳香化合物的特征CnHn^ 系列峰m/z78,65,52,39和(或)m/z77、76、64、63、51、50、38、37。对于末取代的样品及低级烷烃取代的样品,谱图中的基峰为分子离子峰,对于取代基中碳数大于等于3的样品。谱图中的基峰不是分子离子峰,分子离子峰强度随着碳数的增加而降低。这些样品一般容易发生骨架重排,丢失一分子CO,生成1-烷基-2-甲基苯并哒唑正离子。此外,还讨论了谱图中其它的一些碎片离子峰。这对于研究和指导喹喔啉衍生物 的合成,探讨它们在药效及结构特征与生理活性的关系等方面具有重要的应用价值和理论意义。 相似文献
2.
Chaikovskaya O. N. Levin P. P. Sul"timova N. B. Sokolova I. V. Kuz"min A. V. 《Russian Chemical Bulletin》2004,53(2):313-317
The spectra and kinetics of short-lived intermediates formed from aqueous (0.1 N NaOH) solutions of the natural mixture of humic and fulvic acids (HFA) were studied by laser flash photolysis using excitation wavelengths of 337, 390, 470, and 520 nm. Laser photolysis of HFA with light of 520 and 470 nm results in the formation of triplet excited states (THFA) characterized by the broad absorption spectrum with a maximum near 630 nm and lifetimes of 0.15 ms in deoxygenated solutions. The formation of two types of THFA with lifetimes of 0.1 and 2 ms and absorption spectra with maxima at 570 nm is observed under photolysis with light of 337 and 390 nm. The estimation of quantum yields of THFA gives 1 and 0.3% under photolysis with excitation wavelengths of 337 and 520 nm, respectively. The rate constants of THFA quenching by molecular oxygen are equal to (7—8)·108 L mol–1 s–1. 相似文献
3.
The conformational properties and elastic behaviors of protein-like single chains in the process of tensile elongation were investigated by means of Monte Carlo method. The sequences of protein-like single chains contain two types of residues: hydrophobic (H) and hydrophilic (P). The average conformations and thermodynamics statistical properties of protein-like single chains with various elongation ratio λ were calculated. It was found that the mean-square end-to-end distance r increases with elongation ratio,λ. The tensor eigenvalues ratio of : decreases with elongation ratio λ for short (HP)x protein-like polymers, however, the ratio of : increases with elongation ratioλ,especially for long (H)x sequence. Average energy per bond increases with elongation ratioλ, especially for(H)x protein-like single chains. Helmholtz free energy per bond also increases with elongation ratioλ. Elastic force (f), energy contribution to force (fU) and entropy contribution to force (fs) for different protein-like single chains were also calculated.These investigations may provide some insights into elastic behaviors of proteins. 相似文献
4.
The complexity of different quality standards can, in principle, be covered by different approaches and strategies. In-depth
process mapping of quality control (QC) work streams was used by the analytical laboratories of Lonza AG to show up the principle
differences in being compliant to different quality systems. The results identified two main drivers for all necessary actions:
process-related activities and infrastructure-related activities. In addition, a clear indication of the economic impact of
these driving forces was gained, which led the laboratories to decide on a process-oriented approach. This approach has the
advantage of being able to reflect the different demands of different quality assurance (QA) regulations within the same QC
organizational structure. Following the process helps avoid unnecessary efforts in analytical work and represents a very economical
approach, at the same time, providing high flexibility to react to different QA or customer demands.
Received: 5 July 2002 Accepted: 12 November 2002
Acknowledgements The process-oriented approach resulted from many, very challenging discussions for which I would like to thank the staff
of my organization (Analytics & QC), especially, the QA staff and the LIMS team.
Presented at Analytica Conference, 23–26 April 2002, Munich, Germany
Correspondence to B. Ciommer 相似文献
5.
Different charging behaviors between electrons and holes in Si nanocrystals embedded in SiN_x matrix by the influence of near-interface oxide traps 下载免费PDF全文
Si-rich silicon nitride films are prepared by plasma-enhanced chemical vapor deposition method,followed by thermal annealing to form the Si nanocrystals(Si-NCs)embedded in Si Nx floating gate MOS structures.The capacitance–voltage(C–V),current–voltage(I–V),and admittance–voltage(G–V)measurements are used to investigate the charging characteristics.It is found that the maximum flat band voltage shift(△VFB)due to full charged holes(~6.2 V)is much larger than that due to full charged electrons(~1 V).The charging displacement current peaks of electrons and holes can be also observed by the I–V measurements,respectively.From the G–V measurements we find that the hole injection is influenced by the oxide hole traps which are located near the Si O2/Si-substrate interface.Combining the results of C–V and G–V measurements,we find that the hole charging of the Si-NCs occurs via a two-step tunneling mechanism.The evolution of G–V peak originated from oxide traps exhibits the process of hole injection into these defects and transferring to the Si-NCs. 相似文献
6.
Matic Lozinšek Evgeny Goreshnik Anton Meden Gašper Tav?ar 《Journal of solid state chemistry》2009,182(10):2897-2903
In the system BaF2/BF3/PF5/anhydrous hydrogen fluoride (aHF) a compound Ba(BF4)(PF6) was isolated and characterized by Raman spectroscopy and X-ray diffraction on the single crystal. Ba(BF4)(PF6) crystallizes in a hexagonal space group with a=10.2251(4) Å, c=6.1535(4) Å, V=557.17(5) Å3 at 200 K, and Z=3. Both crystallographically independent Ba atoms possess coordination polyhedra in the shape of tri-capped trigonal prisms, which include F atoms from BF4− and PF6− anions. In the analogous system with AsF5 instead of PF5 the compound Ba(BF4)(AsF6) was isolated and characterized. It crystallizes in an orthorhombic Pnma space group with a=10.415(2) Å, b=6.325(3) Å, c=11.8297(17) Å, V=779.3(4) Å3 at 200 K, and Z=4. The coordination around Ba atom is in the shape of slightly distorted tri-capped trigonal prism which includes five F atoms from AsF6− and four F atoms from BF4− anions. When the system BaF2/BF3/AsF5/aHF is made basic with an extra addition of BaF2, the compound Ba2(BF4)2(AsF6)(H3F4) was obtained. It crystallizes in a hexagonal P63/mmc space group with a=6.8709(9) Å, c=17.327(8) Å, V=708.4(4) Å3 at 200 K, and Z=2. The barium environment in the shape of tetra-capped distorted trigonal prism involves 10 F atoms from four BF4−, three AsF6− and three H3F4− anions. All F atoms, except the central atom in H3F4 moiety, act as μ2-bridges yielding a complex 3-D structural network. 相似文献
7.
The novel coordination polymer [Pr(BYBA)3(H2O)2]·[Pr(BYBA)3(H2O)] (BYBAH = 2-benzoylbenzoic acid) was yielded by hydrothermal synthesis, determined by single-crystal X-ray diffraction, and characterized by FT-IR and UV-Vis spectra. The crystal crystallizes in the triclinic system, space group P with a = 9.112(3), b = 14.644(5), c = 27.076(11) (A), α = 84.223(3), β = 87.816(4), γ = 88.902(4)o, V = 3592(2) (A)3, C84H60O21Pr2, Mr = 1687.14, Z = 2, F(000) = 1700, Dc = 1.560 g/cm3, μ = 1.419 mm-1, the final R = 0.0485 and wR = 0.1258 for 13035 observed reflections with I>2((I). The compound contains two different building units, [Pr2(BYBA)6(H2O)4] and [Pr2(BYBA)6(H2O)2]. It is noticeable that [Pr2(BYBA)6(H2O)4] is an isolated binuclear building block, in which the Pr3 ion centers are both located in an eight-coordinated environment. However, in [Pr2(BYBA)6(H2O)2] the Pr3 ion centers are located in a nine-coordinated environment and connected by BYBA ligands to form 1D chains. 相似文献
8.
交联聚乙烯的结晶行为研究 总被引:1,自引:0,他引:1
本论文采用熔融共混法制备了高密度聚乙烯(HDPE)/光引发剂(BDK)/交联剂 (TAIC) 共混物,再用高压汞灯辐照制备一系列不同交联程度的样品。通过广角X射线衍射(XRD)与差示扫描量热法(DSC)等手段研究了紫外光交联对HDPE的晶体结构及非等温结晶动力学行为的影响。研究结果表明:紫外光交联不改变HDPE晶型;随着光交联时间的增加,结晶峰的强度下降;晶粒尺寸变小。随着降温速率的增加,HDPE与交联HDPE (XLPE)的结晶峰变宽,结晶温度(Tp)向低温方向移动,结晶速率变快,结晶度(Xc)下降。相比较而言,XLPE的Tp较低,F(T)较大,Xc较小,结晶活化能(?E)较高,表明紫外光交联抑制了HDPE的结晶。 相似文献
9.
10.
The content and isotopic compositions of different sulphur species in pore-water and solid phases have been examined on five sediment cores taken from muddy sediment region in the Yellow Sea and the East China Sea. Relationships among these data have been investigated with the combination of morphology of mineral pyrite and organic matter so as to role out the diagenetic behaviour of sulphur species at the early stage of diagenesis in modern marine sediment and the origin of pyrite formation. 相似文献