The effect of Mn substitution on thermoelectric properties of Ca3MnxCo4−xO9 at low temperatures

The effects of partial substitution of Mn for Co on the thermoelectric properties of Ca₃Mn_xCo_4−xO₉ (x=0, 0.03, 0.9), prepared by sol-gel process, were investigated at the temperatures from 380 K down to 5 K. The results indicate that the substitution of Mn for Co results in increase in thermopower at temperatures >∼80 K, and substantial (23-31% at 300 K) decrease in lattice thermal conductivity in the whole temperature range investigated. The temperature behavior of ZT suggests that Ca₃Mn_xCo_4−xO₉ with light Mn substitution would be a promising candidate for high-temperature thermoelectric applications.     

Excitons in coupled quantum dots

Properties of excitons in vertically coupled GaAs/AlGaAs quantum dots were investigated using the variational method within the envelope function and effective mass approximations. It was found that when the thickness of the spacer layer becomes less than about one exciton Bohr radius, both the exciton binding energy and the fundamental optical transition energy are reduced compared to those in isolated quantum dots. This is a result of increased space extension of exciton due to the penetration of carrier wave functions into the spacer layer and corresponding reduction in confinement energy which dominates over the Coulomb interaction between the electron and the hole.     

A comparison between optically active CdZnSe/ZnSe and CdZnSe/ZnBeSe self-assembled quantum dots: effect of beryllium

The composition and size of optically active Cd_xZn_1−xSe/ZnSe quantum dots are estimated with a previously developed method. The results are then compared with those obtained for Cd_xZn_1−xSe/Zn_0.97Be_0.03Se QDs. We show that introducing Be into the barrier material enhances both Cd composition and quantum size effect of optically active quantum dots.     

Evolution of Weighted Networks by Duplication-Divergence Mechanism

The duplication and divergence process is ubiquitous in nature and man-made networks. Motivated by the duplication-divergence mechanism which depicts the growth of protein networks, we propose a weighted network model in which topological evolution is coupled with weight dynamics. Large scale numerical results indicate that our model can naturally generate networks with power-law-like distributions of degree, strength and weight. The degree-strength correlation is illustrated as well. These properties are in agreement well with empirical data observed in real-world systems. Furthermore, by altering the retention probability δ, weighted, structured exponential networks are realized.     

Gamow-Teller beta decay of the very neutron-deficientN=50 nuclide98Cd

For the first time, detailed decay-spectroscopic investigations were performed for the very neutron-deficientN=50 nuclide⁹⁸Cd. The⁹⁸Cd activity was produced in spallation reactions between 600 MeV protons and a natural tin target, yielding a⁹⁸Cd beam intensity of 10 to 60 atoms/s at the collector of the ISOLDE massseparator. By means of-ray and conversion-electron spectroscopy, 19 transitions were found to follow the ⁺/EC decay⁹⁸Cd⁹⁸Ag. The transitions at 61 and 107 keV were shown to beM1(+E2) andE2, respectively, and the⁹⁸Cd half-life was measured as 9.2±0.3 s. TheQ _EC value of⁹⁸Cd is determined semiempirically and is compared to model predictions together with the measuredQ _EC values of the neighbouring cadmium isotopes^100,102Cd and theN=50 isotones⁹²Mo,⁹⁴Ru, and⁹⁶Pd, taken from the literature. The newly established decay scheme of⁹⁸Cd includes 9 excited states of⁹⁸Ag. Four states at 1691, 1861, 2164, and 2544 keV are directly fed by 0⁺ 1⁺ Gamow-Teller beta transitions with a summed strength of 3.5 _–0.7 ^+0.8 . This value corresponds to 25±5% of the strength predicted for the GT transformation of a g_9/2 proton (in⁹⁸Cd) into a g_7/2 neutron (in⁹⁸Ag) by the extreme single-particle shell model. The GT-strength splitting and quenching, observed for⁹⁸Cd, are compared with the corresponding data for lighter even-even N=50 isotones, and are discussed with reference to the predictions of more sophisticated nuclear models. We find that only in some cases it is possible to explain qualitatively the observed GT strength distribution and its total magnitude without renormalizing the free-neutron value of the axial-vector coupling constant.Dedicated to Prof. P. Armbruster on the occasion of his 60th birthday     

Pulsed power modeling of very-large-aperture,transverse-discharge CO2 lasers

Discharge behavior of large-aperture (10–70 cm) CO₂ lasers is computed using a coupled particle kinetics-equivalent circuit model. Pulsed power systems that produce a single excitation pulse are only able to satisfy the preionization, ignition, and impedance matching conditions for interelectrode gaps 40–50 cm. Double-pulse systems are required for larger gaps, not only to optimize electrical efficiency, but to avoid oscillatory behavior which can lead to arc formation during the second cycle.     

Functionalization and bioactivity in vitro of mesoporous bioactive glasses

Amino and carboxylic groups functionalized mesoporous bioactive glasses (denoted as N-MBGs and C-MBGs, respectively) were successfully synthesized through a post-grafting process and characterized by XRD, N₂ sorption, TEM, FT-IR and TG techniques. Their in vitro bioactivity and degradation behavior were investigated in simulated body fluid and examined by various techniques. The results demonstrate that the bioactivity of all the samples and the morphology of carbonated hydroxyapatite were affected remarkably by the introduction of functional groups. Spherical carbonated hydroxyapatite particles were observed grown on the N-MBGs surfaces after soaking in simulated body fluid for 8 h, which is different from the rod-like carbonated hydroxyapatite grown on conventional mesoporous bioactive glasses. While for C-MBGs, the nucleation and growth rate of carbonated hydroxyapatite was decreased at increased contents of carboxylic groups.     

Incompatibility networks as models of scale-free small-world graphs

We make a mapping from Sierpinski fractals to a new class of networks, the incompatibility networks, which are scale-free, small-world, disassortative, and maximal planar graphs. Some relevant characteristics of the networks such as degree distribution, clustering coefficient, average path length, and degree correlations are computed analytically and found to be peculiarly rich. The method of network representation can be applied to some real-life systems making it possible to study the complexity of real networked systems within the framework of complex network theory.     

Multifractal detrended fluctuation analysis of derivative and spot markets

We investigate the multifractal properties of price increments in the cases of derivative and spot markets. Through the multifractal detrended fluctuation analysis, we estimate the generalized Hurst and the Renyi exponents for price fluctuations. By deriving the singularity spectrum from the above exponents, we quantify the multifractality of a financial time series and compare the multifractal properties of two different markets. The different behavior of each agent-group in transactions is also discussed. In order to identify the nature of the underlying multifractality, we apply the method of surrogate data to both sets of financial data. It is shown that multifractality due to a fat-tailed distribution is significant.     

Other-regarding preference and the evolutionary prisoner’s dilemma on complex networks

Prevailing models of the evolutionary prisoner’s game on networks always assume that agents are pursuing their own profit maximization. But the results from experimental games show that many agents have other-regarding preference. In this paper, we study the emergence of cooperation from the prisoner’s dilemma game on complex networks while some agents exhibit other-regarding preference such as inequality aversion, envious and guilty emotions. Contrary to common ideas, the simulation results show that the existence of inequality aversion agents does not promote cooperation emergence on a BA (Barabási and Albert) scale-free network in most situations. If the defection attraction is big and agents exhibit strong preference for inequality aversion, the frequency of cooperators will be lower than in situations where no inequality aversion agents exist. In some cases, the existence of the inequality agents will even induce the frequency of cooperators to zero, a feature which is not observed in previous research on the prisoner’s dilemma game when the underlying interaction topology is a BA scale-free network. This means that if an agent cares about equality too much, it will be difficult for cooperation to emerge and the frequency of cooperators will be low on BA networks. The research on the effect of envy or guilty emotions on the emergence of cooperation in the prisoner’s dilemma game on BA networks obtains similar results, though some differences exist. However, simulation results on a WS (Watts and Strogatz) small-world network display another scenario. If agents care about the inequality of agents very much, the WS network favors cooperation emergence in the prisoners’ dilemma game when other-regarding agents exist. If the agent weight on other-regarding is lowered, the cooperation frequencies emerging on a WS network are not much different from those in situations without other-regarding agents, although the frequency of cooperators is lower than those of the situation without other-regarding preference agents sometimes. All the simulation results imply that inequality aversion and its variations can have important effects on cooperation emergence in the prisoner’s dilemma game, and different network topologies have different effects on cooperation emergence in the prisoner’s dilemma game played on complex networks.