Fast determination of critical eluent composition for polymers by gradient chromatography

Gradient chromatography was applied in order to calculate the composition at elution for different methacrylates on normal phase columns. In addition the composition at elution was determined for polyethyleneoxide on a reverse phase column. It is shown that high molar mass polymers elute for a given homopolymer irrespective of their molar mass at the same eluent composition, which varies only slightly with gradient slope. In general the composition at elution in gradient chromatography is expected to be slightly lower than the true critical composition. For high molar mass polymers we found this composition to be close to the critical composition determined by isocratic experiments. The difference between the composition at elution and the true critical composition for a variety of polymethacrylates and for polyethyleneglycol was found to be only between 0.2 and 5%. Thus, after estimating the composition at elution, only a small number of additional isocratic experiments is needed to find the exact critical composition.     

Structural and Superconducting Property Variations with Nominal Mg Non‐Stoichiometry in MgxB2 and Its Enhancement of Upper Critical Field

By applying a combination of characterisation tools, changes in structural and superconducting properties with nominal Mg non‐stoichiometry in Mg_xB₂ are found. The non‐stoichiometry produces enhanced in‐field critical current densities (J_c's) and upper critical field / irreversibility field (H_c2/H_irr(T)) values. Upper critical fields of ～ 21 T (4.2 K) were obtained in nominal Mg‐deficient samples compared to ～ 17 T (4.2 K) for near‐stoichiometric samples.     

Critical heat flux on a flat plate heater located at the middle of a duct in forced flow of pressurized He II

Critical heat fluxes (CHFs) were measured for two types of rectangular ducts containing horizontal flat plate heaters. One has the flat plate heater of 6 mm wide and 20 mm long located on the inner lower wall at 50 mm from the inlet. The other duct has two horizontal flat plates of 6 mm wide and 20 mm long on inner upper and lower walls at 50 mm from the inlet. The equation of CHF for the forced convection containing a new nondimensional-parameter m introduced in order to calculate cross-sectionally averaged liquid temperature at the center of the duct was derived based on two fluid model, ordinary convection theorem and experimental results. It was confirmed that this correlation can describe not only the author's data on the duct but also other worker's data for channels with different shapes and sizes.     

Theoretical Analysis of Critical period in Microbend Fiberoptic Sensor

1IntrodctionThesdV8fltsg6Sofffi1CY0bCfldf山CY0ptlCS6fiS0f8f6lflt6llSltyffiDdU18tlflgsliddCtCCtlflg，simpletechnique，highrellabllltyandlowprice，thereformlcrobendfiberoptlcsensorIswidelyusedtomeasurementofstrain，stressandv比rationetc．Inpractice，thesensltlvltyofsensorIsaveryimportantparameter，andthesensltlvltyofmlcrobendf山eroptlcsensorIsmainlyrelat-6dtofoil0WlflgthY66f8CtofS［‘-：ffilCfob6fldsffiplltlld6：fillffib6yofthlCY0b6fldS6Ct10llSsfldffil-crobendperiod，andmlcrobendperio…     

On the hollowness ratio effect on the dynamics of a spinning Rayleigh beam

The analytical solutions of a spinning Rayleigh beam with rotatory moment inertia and gyroscopic effect are presented in this paper. The critical speeds can be written analytically in a function of the length-to-radius ratio (l) defined by the beam's length over its outer radius and the hollowness ratio (α) defined by the hollow area over the total area of the cross section. The sensitivity analyses show that the critical speed is decreasing with l, but increasing with α. Moreover, α is more sensitive to the critical speeds. The design of a spinning beam should therefore be emphasized more on the hollowness factor. Contrary to common belief, only finite critical speeds exist and the number is independent of the boundary conditions. It increases monotonically with l, but decreases with α. The steady state unbalanced response can therefore be expressed analytically by the finite precessional modes and the corresponding generalized coordinates.     

Maintenance strategy based on a multicriterion classification of equipments

In an industrial plant, the level of maintenance provided to individual equipment is directly related to the availability that is expected from it. Thus, it is hoped that the most critical equipments will not fail or, at least, that any failure will be rapidly detected and corrected in the minimum time possible. Since resources are limited, it is necessary to determine how they should be distributed, so that no important equipment remains neglected while more resources are concentrated on the most critical items. Therefore, it is necessary to classify equipment in an objective way according to its importance. The method of multicriterion classification of critical equipments (MCCE)², which is described in the present work, allows systematic and detailed quantification of the criticality of all equipment, that is to say, it provides an evaluation of the importance that its correct operation has for the plant. To provide this information, the consequences for a company of any failure in the equipment concerned are analysed. Finally, a real case example of an urban wastewater treatment plant is described, in which the MCCE method is applied.     

压水堆硼稀释事故的计算

一、概述核电厂压水堆的初始过剩反应性是通过控制捧、固体可燃毒物和溶解在主回路冷却剂中的硼酸等三种方式联合控制的。随着反应堆的燃耗和裂变毒物的积累,堆的过剩反应性不断减少,需要通过化容系统,控制硼酸的浓度来进行补偿。如果化容系统发生故障或操作员误操作,就会给回路注入无硼或低于规定浓度的补给水,给反应堆引入正反应性,造成硼稀释事故。按核安全法规的要求,应对换料、冷停堆、热停堆和启动等工况进行计算,并要求在这些     

西安脉冲堆计算值和实测结果分析

介绍了西安脉冲堆堆芯布置、计算模型和程序以及计算值与实验测量结果分析。西安脉冲堆在满功率（2MW）下连续运行了72小时，证明西安脉冲堆整个系统和设备是良好的、安全可靠的。根据西安脉冲堆计算值与测量值的比较，证明计算程序可靠，具有较高精度。西安脉冲堆理论计算值与实验测量值符合较好，完全满足工程设计要求，实验测量结果达到了设计指标的要求。     

一种光时分制交换时隙分配计算算法

介绍了一种专为时分复用系统设计的时院分配计算算法。这种算法中主要用到的技术是从一个话务矩阵的各行选出一个区别代表的系统方法。对于任何话务矩阵，这种算法的分配效率都能达到１００％，所产生的模式矩阵个数最多为ｎ２－２ｎ＋２个（对于ｎ×ｎ矩阵）。     

Spatiotemporal aspects of jerky flow in Al–Mg alloys, in relation with the Mg content

The spatiotemporal aspects of the Portevin–Le Chatelier effect in Al–Mg alloys are investigated using direct observations of the sample surface with a digital camera. Optical measurements of the surface profile using a white light interferometer allow the estimation of the local strain and strain rate associated with the bands. The effect of Mg content on instability characteristics is analyzed. The reloading time is shown to depend on the Mg content only at the strain and strain rates where type C bands are observed.